Cooperative Supramolecular Polymerization Driven by Metallophilic Pd•••Pd Interactions

被引：128
|
作者：
Mayoral, Maria Jose [1 ,2 ]
Rest, Christina [1 ,2 ]
Stepanenko, Vladimir [1 ,2 ]
Schellheimer, Jennifer [1 ,2 ]
Albuquerque, Rodrigo Q. [3 ]
Fernandez, Gustavo [1 ,2 ]
机构：
[1] Univ Wurzburg, Inst Organ Chem, Wurzburg, Germany
[2] Univ Wurzburg, Ctr Nanosyst Chem, Wurzburg, Germany
[3] Univ Sao Paulo, Inst Chem Sao Carlos, Sao Carlos, SP, Brazil
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 06期
关键词：
METAL-METAL INTERACTIONS; LIQUID-CRYSTALLINE COMPLEXES; PI-PI INTERACTIONS; NUCLEATION-ELONGATION; PT-II; AMPLIFICATION; PLATINUM(II); PALLADIUM(II); TRANSITION; ASSEMBLIES;
D O I：
10.1021/ja312628g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new oligophenyleneethynylene (OPE)based Pd(II) pyridyl complex has been synthesized, and its self-assembly has been investigated in solution, in the bulk state, and on surfaces. Detailed analysis of concentration- and temperature-dependent UV-vis studies in methylcyclohexane supported by DFT calculations demonstrate for the first time that cooperative supramolecular polymerization processes can be driven by metallophilic interactions.
引用
收藏
页码：2148 / 2151
页数：4
相关论文
共 50 条
  • [21] Pion production in pd interactions
    Greiff, J
    Koch, I
    Rohdjess, H
    Scobel, W
    ACTA PHYSICA POLONICA B, 1996, 27 (11): : 2965 - 2969
  • [22] DRUG INTERACTIONS - HANSTEN,PD
    DORFMAN, W
    PSYCHOSOMATICS, 1977, 18 (01) : 60 - 60
  • [23] Nucleation-elongation: a mechanism for cooperative supramolecular polymerization
    Zhao, DH
    Moore, JS
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2003, 1 (20) : 3471 - 3491
  • [24] Enzymatic Reaction-Coupled, Cooperative Supramolecular Polymerization
    Das, Angshuman
    Ghosh, Saikat
    Mishra, Ananya
    Som, Arka
    Banakar, Vijay Basavaraj
    Agasti, Sarit S.
    George, Subi J.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2024, 146 (21) : 14844 - 14855
  • [25] Octapi Interactions: Self-Assembly of a Pd-Based [2]Catenane Driven by Eightfold π Interactions
    Lu, Jinzhen
    Turner, David R.
    Harding, Lindsay P.
    Byrne, Lindsay T.
    Baker, Murray V.
    Batten, Stuart R.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (30) : 10372 - +
  • [26] Coordination-Driven Polymerization of Supramolecular Nanocages
    Ma, Jian-Gong, 1600, American Chemical Society (137):
  • [27] Dealkoxylation ofN-alkoxyamides without an external reductant driven by Pd/Al cooperative catalysis
    Suzuki, Hirotsugu
    Shiomi, Takahiro
    Yoneoka, Kenji
    Matsuda, Takanori
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2020, 18 (38) : 7545 - 7548
  • [28] PAIRWISE FINAL STATE INTERACTIONS IN THE pd → pdη REACTION NEAR THRESHOLD
    Upadhyay, N. J.
    Jain, B. K.
    Khemchandani, K. P.
    Kelkar, N. G.
    MODERN PHYSICS LETTERS A, 2009, 24 (29) : 2319 - 2329
  • [29] RADIOTRACER STUDIES ON THE INTERACTIONS OF HYDROGEN WITH PD/C AND PD BLACK CATALYSTS
    LOH, KL
    HONG, CM
    TANG, YN
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1983, 186 (AUG): : 61 - COLL
  • [30] Coordination-Driven Polymerization of Supramolecular Nanocages
    Niu, Zheng
    Fang, Sheng
    Liu, Xiao
    Ma, Jian-Gong
    Ma, Shengqian
    Cheng, Peng
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (47) : 14873 - 14876
12345