Cooperative Supramolecular Polymerization Driven by Metallophilic Pd•••Pd Interactions

被引：128
|
作者：
Mayoral, Maria Jose [1 ,2 ]
Rest, Christina [1 ,2 ]
Stepanenko, Vladimir [1 ,2 ]
Schellheimer, Jennifer [1 ,2 ]
Albuquerque, Rodrigo Q. [3 ]
Fernandez, Gustavo [1 ,2 ]
机构：
[1] Univ Wurzburg, Inst Organ Chem, Wurzburg, Germany
[2] Univ Wurzburg, Ctr Nanosyst Chem, Wurzburg, Germany
[3] Univ Sao Paulo, Inst Chem Sao Carlos, Sao Carlos, SP, Brazil
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 06期
关键词：
METAL-METAL INTERACTIONS; LIQUID-CRYSTALLINE COMPLEXES; PI-PI INTERACTIONS; NUCLEATION-ELONGATION; PT-II; AMPLIFICATION; PLATINUM(II); PALLADIUM(II); TRANSITION; ASSEMBLIES;
D O I：
10.1021/ja312628g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new oligophenyleneethynylene (OPE)based Pd(II) pyridyl complex has been synthesized, and its self-assembly has been investigated in solution, in the bulk state, and on surfaces. Detailed analysis of concentration- and temperature-dependent UV-vis studies in methylcyclohexane supported by DFT calculations demonstrate for the first time that cooperative supramolecular polymerization processes can be driven by metallophilic interactions.
引用
收藏
页码：2148 / 2151
页数：4
相关论文
共 50 条
  • [1] Cooperative supramolecular polymerization: Influence of metallophilic interactions and self-sorting processes
    Fernandez, Gustavo
    Mayoral, Maria Jose
    Stepanenko, Vladimir
    Rest, Christina
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 246
  • [2] Hg(II)•••Pd(II) metallophilic interactions
    Kim, Mieock
    Taylor, Thomas J.
    Gabbai, Francois P.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (20) : 6332 - +
  • [3] Cooperative Supramolecular Polymerization Guided by Dispersive Interactions
    Kotha, Srinu
    Sahu, Rahul
    Srideep, Dasari
    Yamijala, Sharma S. R. K. C.
    Kumar Reddy, Sandeep
    Venkata Rao, Kotagiri
    CHEMISTRY-AN ASIAN JOURNAL, 2022, 17 (16)
  • [4] Supramolecular alternate co-assembly driven by metallophilic Pt ... Pt interactions
    Zhao, Gao
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 254
  • [5] Polymerization via Pd/norbornene cooperative catalysis
    Yoon, Ki-Young
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 256
  • [6] Dipole-Moment-Driven Cooperative Supramolecular Polymerization
    Kulkarni, Chidambar
    Bejagam, Karteek K.
    Senanayak, Satyaprasad P.
    Narayan, K. S.
    Balasubramanian, S.
    George, Subi J.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (11) : 3924 - 3932
  • [7] Trends in Metallophilic Bonding in Pd-Zn and Pd-Cu Complexes
    Paenurk, Eno
    Gershoni-Poranne, Renana
    Chen, Peter
    ORGANOMETALLICS, 2017, 36 (24) : 4854 - 4863
  • [8] Supramolecular Gold Metallogelators: The Key Role of Metallophilic Interactions
    Lima, Joao Carlos
    Rodriguez, Laura
    INORGANICS, 2015, 3 (01): : 1 - 18
  • [9] Selenadiazolopyridine: A Synthon for Supramolecular Assembly and Complexes with Metallophilic Interactions
    Mukherjee, Goutam
    Singh, Puspendra
    Ganguri, Chandrasekhar
    Sharma, Sagar
    Singh, Harkesh B.
    Goel, Nidhi
    Singh, Udai P.
    Butcher, Ray J.
    INORGANIC CHEMISTRY, 2012, 51 (15) : 8128 - 8140
  • [10] Kinetically Driven Cooperative Supramolecular Polymerization of Bisterpyridine Ligands in Aqueous Solution
    Park, Yumi
    Kim, Juyeong
    Jung, Jong Hwa
    MACROMOLECULAR RAPID COMMUNICATIONS, 2025,
12345