Synthesis of organometallic solids by protonation of Cp*M(CN)3n- (M = Rh, Ir, Ru)

被引：5
|
作者：
Contakes, SM
Schmidt, M
Rauchfuss, TB [1 ]
机构：
[1] Univ Illinois, Sch Chem Sci, Urbana, IL 61801 USA
[2] Univ Illinois, Frederick Seitz Mat Res Lab, Urbana, IL 61801 USA
来源：
CHEMICAL COMMUNICATIONS | 1999年 / 13期
关键词：
D O I：
10.1039/a902115i
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Protonation of aqueous acetone solutions of [Cp*Ir(CN)(3)](-) produces the two-dimensional organometallic solid (H3O)-[Cp*Ir(CN)(3)]. Me2CO wherein 14 Angstrom diameter channels (Ir4C8N8O4) contain exchangeable solvent molecules; the analogous Ru and Rh tricyanide complexes are also susceptible to proton-induced polymerization.
引用
收藏
页码：1183 / 1184
页数：2
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