Enhanced electrochromic characteristics induced by Au/PEDOT/Pt microtubes in WO3 based electrochromic devices

被引:31
|
作者
Karaca, Gozde Yurdabak [1 ]
Eren, Esin [1 ,2 ]
Cogal, Gamze Celik [1 ]
Uygun, Emre [3 ]
Oksuz, Lutfi [4 ]
Oksuz, Aysegul Uygun [1 ]
机构
[1] Suleyman Demirel Univ, Fac Arts & Sci, Dept Chem, TR-32260 Isparta, Turkey
[2] Suleyman Demirel Univ, Innovat Technol Applicat & Res Ctr, TR-32260 Isparta, Turkey
[3] Suleyman Demirel Univ, Fac Engn, Dept Civil Engn, TR-32260 Isparta, Turkey
[4] Suleyman Demirel Univ, Fac Arts & Sci, Dept Phys, TR-32260 Isparta, Turkey
关键词
PEDOT; Microtube; Template method; WO3; Electrochromic; THIN-FILMS; FACILE PREPARATION; HIGH-CONTRAST; PERFORMANCE; ARRAYS; NANOPARTICLES; NANOWIRES; IMPEDANCE; GROWTH; V2O5;
D O I
10.1016/j.optmat.2018.11.052
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A study has been carried out on improving electrochromic performances of tungsten trioxide (WO3) thin films based electrochromic devices (ECDs) with inclusion of gold/poly (3, 4-ethylenedioxythiophene)/platinum (Au/PEDOT/Pt) microtubes. The deposited film characteristics were evaluated using scanning electron microscopy-energy-dispersive X-ray spectroscopy (SEM-EDS). SEM results indicated that homogeneous spreading of Au/PEDOT/Pt microtubes are successfully obtained onto the WO3 layer. The electrochromic performances such as electrochromic contrast, response times and charge transfer resistance were investigated and compared with Au/PEDOT/Pt microtubes-free system in detail. Higher optical contrast (26%) and faster response times (bleaching time (t(b)): 13.83 s, coloration time (t(c)): 19.25 s) were obtained for electrochromic device made from Au/PEDOT/Pt microtubes against an applied potential of +/- 2 V. Especially, Au/PEDOT/Pt microtubes-based ECD exhibited stronger electrochromic color change from transparent to blue.
引用
收藏
页码:472 / 478
页数:7
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