Synthesis and photochemical properties of phthalocyanine zinc(II) complexes containing o-carborane units

被引：35

作者：

Woehrle, Dieter ^{[1
]}

Tsaryova, Olga ^{[1
]}

Semioshkin, Andrey ^{[2
]}

Gabel, Detlef ^{[1
]}

Suvorova, Olga ^{[3
]}

机构：

[1] Univ Bremen, Fac Biol & Chem, D-28334 Bremen, Germany

[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

[3] Russian Acad Sci, GA Razuvaev Inst Organometall Chem, Nizhnii Novgorod, Russia

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2013年 / 747卷

关键词：

Phthalocyanine zinc; o-Carborane; Singlet oxygen; Photooxidation; Citronellol; NEUTRON-CAPTURE THERAPY; POLYHEDRAL BORON-COMPOUNDS; OXYGEN QUANTUM YIELDS; PHOTODYNAMIC THERAPY; PHOTOSENSITIZERS; DERIVATIVES; PHOTOOXIDATIONS; CHEMISTRY; METAL;

D O I：

10.1016/j.jorganchem.2013.03.020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and characterization of novel phthalocyanine zinc(II) complexes containing o-carborane units are described. The following properties of o-carboranyl-substituted phthalocyanines were investigated: singlet oxygen quantum yield, photo-oxidative stability, photocatalytic activity in the photooxidation of (S)-(-)-citronellol. The o-carboranyl substituted phthalocyanine zinc(II) complexes exhibit improved singlet oxygen quantum yields, photo-oxidative stabilities, photocatalytic activities compared to phthalocyanine zinc(II) complexes without o-carboranyl groups. Therefore these o-carboranyl complexes are of interest for use in cancer therapy. (C) 2013 Elsevier B. V. All rights reserved.

引用

页码：98 / 105

页数：8

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