Contribution from two types of peroxyl radicals to cyclohexanol oxidation and their reactivity

被引：12
|
作者：
Moskvitina, E. G. [1 ]
Puchkov, S. V. [1 ]
Borisov, I. M. [2 ]
Perkel', A. L. [1 ]
机构：
[1] Kuzbass State Tech Univ, Fac Chem & Technol, Kemerovo 650000, Russia
[2] Bashkir State Pedag Univ, Fac Nat Sci & Geog, Ufa 450000, Bashkortostan, Russia
来源：
KINETICS AND CATALYSIS | 2012年 / 53卷 / 03期
关键词：
LIQUID-PHASE OXIDATION; CH BONDS; NITROBENZENE; ALCOHOLS;
D O I：
10.1134/S002315841203010X
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The oxygen uptake kinetics in the liquid-phase oxidation of cyclohexanol initiated by cumyl peroxide in the presence of inhibitors (ionol and nitrobenzene) has been investigated (373 K, ortho-dichlorobenzene as the solvent). The relative contributions from the hydroperoxyl and alpha-hydroxycyclohexylperoxyl radicals to chain propagation has been determined. The rate constants for the reactions of these radicals with the alcohol have been determined.
引用
收藏
页码：287 / 296
页数：10
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