Contribution from two types of peroxyl radicals to cyclohexanol oxidation and their reactivity

被引：12
|
作者：
Moskvitina, E. G. [1 ]
Puchkov, S. V. [1 ]
Borisov, I. M. [2 ]
Perkel', A. L. [1 ]
机构：
[1] Kuzbass State Tech Univ, Fac Chem & Technol, Kemerovo 650000, Russia
[2] Bashkir State Pedag Univ, Fac Nat Sci & Geog, Ufa 450000, Bashkortostan, Russia
来源：
KINETICS AND CATALYSIS | 2012年 / 53卷 / 03期
关键词：
LIQUID-PHASE OXIDATION; CH BONDS; NITROBENZENE; ALCOHOLS;
D O I：
10.1134/S002315841203010X
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The oxygen uptake kinetics in the liquid-phase oxidation of cyclohexanol initiated by cumyl peroxide in the presence of inhibitors (ionol and nitrobenzene) has been investigated (373 K, ortho-dichlorobenzene as the solvent). The relative contributions from the hydroperoxyl and alpha-hydroxycyclohexylperoxyl radicals to chain propagation has been determined. The rate constants for the reactions of these radicals with the alcohol have been determined.
引用
收藏
页码：287 / 296
页数：10
相关论文
共 50 条
  • [1] Contribution from two types of peroxyl radicals to cyclohexanol oxidation and their reactivity
    E. G. Moskvitina
    S. V. Puchkov
    I. M. Borisov
    A. L. Perkel’
    Kinetics and Catalysis, 2012, 53 : 287 - 296
  • [2] Oxidation of alcohols involving two types of peroxyl radicals
    Denisov, E. T.
    Denisova, T. G.
    PETROLEUM CHEMISTRY, 2006, 46 (05) : 305 - 313
  • [3] Oxidation of alcohols involving two types of peroxyl radicals
    E. T. Denisov
    T. G. Denisova
    Petroleum Chemistry, 2006, 46 : 305 - 313
  • [4] Kinetic analysis of the reactivity of peroxyl radicals in chain oxidation of unsaturated compounds
    Eugene Pliss
    Tamara Pokidova
    Andrey Sirik
    Alexey Grobov
    Nikita Pitsyn
    Viacheslav Machtin
    Mikhail Soloviev
    Mikhail Berezin
    Reaction Kinetics, Mechanisms and Catalysis, 2024, 137 : 53 - 76
  • [5] Reactivity of α-amino-peroxyl radicals and consequences for amine oxidation chemistry
    Schuemperli, Martin T.
    Hammond, Ceri
    Hermans, Ive
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (31) : 11002 - 11007
  • [6] Kinetic analysis of the reactivity of peroxyl radicals in chain oxidation of unsaturated compounds
    Pliss, Eugene
    Pokidova, Tamara
    Sirik, Andrey
    Grobov, Alexey
    Pitsyn, Nikita
    Machtin, Viacheslav
    Soloviev, Mikhail
    Berezin, Mikhail
    REACTION KINETICS MECHANISMS AND CATALYSIS, 2024, 137 (01) : 53 - 76
  • [7] New access to the peroxyl radicals reactivity?
    Lalevee, J.
    Allonas, X.
    Fouassier, J. P.
    CHEMICAL PHYSICS LETTERS, 2007, 445 (1-3) : 62 - 67
  • [8] REACTIVITY BETWEEN PEROXYL RADICALS IN REACTIONS
    TAVADYAN, LA
    KHIMICHESKAYA FIZIKA, 1991, 10 (05): : 650 - 658
  • [9] Reactivity of hydroxynaphthalenes towards peroxyl radicals
    Pino, E.
    Aspee, A.
    Lopez-Alarcon, C.
    Lissi, E.
    JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 2006, 19 (12) : 867 - 873
  • [10] Generation and reactivity of nucleoside peroxyl radicals.
    Tallman, KA
    Tronche, C
    Greenberg, MM
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 216 : U456 - U456
12345