Platinum(II)-bis(9-methyladenine) complexes;: N1 → N6 migration of Pt(II) vs deamination of coordinated methyladenine

被引：14
|
作者：
Klika, KD [1 ]
Arpalahti, J [1 ]
机构：
[1] Univ Turku, Dept Chem, FIN-20014 Turku, Finland
来源：
CHEMICAL COMMUNICATIONS | 2004年 / 06期
关键词：
D O I：
10.1039/b315987f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Stepwise migration of coordinated Pt(II) from the endocyclic N1 site to the exocyclic amino group occurs in the bis(9-methyladenine-N-1) complex of cis-Pt-II(NH3)(2) in basic solution, whereafter deamination of the 9-methyladenine still coordinated at N-1 competes with a second migration step.
引用
收藏
页码：666 / 667
页数：2
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