Synthesis and luminescence behaviour of mixed-metal rhenium(I)-copper(I) and -silver(I) alkynyl complexes.: X-Ray crystal structures of [{η2-Re(Co)3(bpy)(CCPh)}2Cu]PF6 and [{η2-Re(CO)3(bpy)(CCPH)}2Ag]PF6

被引:39
|
作者
Yam, VWW [1 ]
Chong, SHF [1 ]
Wong, KMC [1 ]
Cheung, KK [1 ]
机构
[1] Univ Hong Kong, Dept Chem, Hong Kong, Peoples R China
关键词
D O I
10.1039/a902273b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two mixed-metal rhenium(I)-copper(I) and -silver(I) alkynyl complexes, [{eta(2)-Re(CO)(3)(bpy)(C=CPh)}(2)Cu]PF6 1 and [{eta(2)-Re(CO)(3)(bpy)(C=CPh)}(2)Ag]PF6 2, have been synthesized and shown to exhibit rich luminescence behaviour; the X-ray crystal structures of both complexes have also been determined.
引用
收藏
页码:1013 / 1014
页数:2
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