Conductive Network Formation and Electrical Properties of Poly(vinylidene fluoride)/Multiwalled Carbon Nanotube Composites: Percolation and Dynamic Percolation

被引：28
|
作者：
Zhang, Cheng [1 ]
Zhu, Jun [1 ]
Ouyang, Mi [1 ]
Ma, Chunan [1 ]
Sumita, Masao [2 ]
机构：
[1] Zhejiang Univ Technol, State Key Lab Breeding Base Green Chem Synth Tech, Coll Chem Engn & Mat Sci, Hangzhou 310014, Zhejiang, Peoples R China
[2] Tokyo Inst Technol, Dept Chem & Mat Sci, Meguro Ku, Tokyo 1528552, Japan
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 2009年 / 114卷 / 03期
基金：
中国国家自然科学基金;
关键词：
multiwalled carbon nanotubes; dynamic percolation; poly(vinylidene fluoride); conductive network; electrical resistivity; POLYMER COMPOSITES; MECHANICAL-PROPERTIES; BLACK; POLYETHYLENE; TEMPERATURE; BLENDS; TIME; FUNCTIONALIZATION; AGGLOMERATION; POLYSTYRENE;
D O I：
10.1002/app.30729
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Conductive network formation and its dynamic process for multiwalled carbon nanotubes (MWNTs) and carboxyl-tethered MWNT (MWNT-COOH) filled poly(vinylidene fluoride)(PVDF) systems were investigated. Based on real-time tracing the variation of electrical resistivity of systems with isothermal treatment time, the conductive network formation was evaluated. It was found that the conductive network formation was temperature and time dependent. The percolation time, characterized at a certain annealing time where the electrical resistivity started to decrease drastically, decreased with the increase of the filler concentration or the annealing temperature. However, the values of the percolation time and the activation energy of conductive network formation for the PVDF/MWNT-COOH system were higher than those of the PVDF/MWNT system, indicating that the interaction between MWNTs and PVDF molecules played an important role in the conductive network formation of the composites. Furthermore, a modified thermodynamic percolation model was proposed to predict the percolation time of PVDF/MWNT composites. It was found that the calculated results fit the experimental data very well. (C) 2009 Wiley Periodicals, Inc. J Appl Polym Sci 114: 1405-1411, 2009
引用
收藏
页码：1405 / 1411
页数：7
相关论文
共 50 条
  • [21] Electrochromic behavior and electrical percolation threshold of carbon nanotube/poly(pyridinium triflate) composites
    Pichugov, Roman D.
    Malyshkina, Inna A.
    Makhaeva, Elena E.
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2018, 823 : 601 - 609
  • [22] Dynamic Electrical and Rheological Percolation in Isotactic Poly(propylene)/Carbon Black Composites
    Huang, Shilin
    Liu, Zhengying
    Yin, Chaolu
    Wang, Yu
    Gao, Yongjuan
    Chen, Chen
    Yang, Mingbo
    MACROMOLECULAR MATERIALS AND ENGINEERING, 2012, 297 (01) : 51 - 59
  • [23] A review and analysis of electrical percolation in carbon nanotube polymer composites
    Bauhofer, Wolfgang
    Kovacs, Josef Z.
    COMPOSITES SCIENCE AND TECHNOLOGY, 2009, 69 (10) : 1486 - 1498
  • [24] Achieving electrical percolation in polymer-carbon nanotube composites
    Rahatekar, SS
    Hamm, M
    Shaffer, MSP
    Elliott, JA
    CONTINUOUS NANOPHASE AND NANOSTRUCTURED MATERIALS, 2004, 788 : 271 - 276
  • [25] Nano carbon powder-multiwalled carbon nanotubes/poly(vinylidene fluoride) percolating composites with low-percolation binary functional phases and negative permittivity
    Shi, Guangyue
    Liu, Yao
    POLYMER COMPOSITES, 2025,
  • [26] Tailoring the hybrid network structure of boron nitride/carbon nanotube to achieve thermally conductive poly(vinylidene fluoride) composites
    Qi, Xiao-dong
    Wang, Wen-yan
    Xiao, Yan-jun
    Huang, Ting
    Zhang, Nan
    Yang, Jing-hui
    Wang, Yong
    COMPOSITES COMMUNICATIONS, 2019, 13 : 30 - 36
  • [27] Crystallization Kinetics of Multiwalled Carbon Nanotube Filled Poly ( vinylidene fluoride) Composites: Influence of Interfacial Interactions
    Liu, Xi-Qiang
    Li, Ruo-Han
    Pang, Yuan-Jin
    Ni, Hai-Ying
    Chen, Jun
    POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2014, 53 (06) : 539 - 549
  • [28] Influence of conductive network structure on the EMI shielding and electrical percolation of carbon nanotube/polymer nanocomposites
    Al-Saleh, Mohammed H.
    SYNTHETIC METALS, 2015, 205 : 78 - 84
  • [29] Electrical behavior of polypropylene/multiwalled carbon nanotube nanocomposites with low percolation threshold
    Tjong, S. C.
    Liang, G. D.
    Bao, S. P.
    SCRIPTA MATERIALIA, 2007, 57 (06) : 461 - 464
  • [30] Graphene/poly(vinylidene fluoride) composites with high dielectric constant and low percolation threshold
    Fan, Ping
    Wang, Lei
    Yang, Jintao
    Chen, Feng
    Zhong, Mingqiang
    NANOTECHNOLOGY, 2012, 23 (36)
12345