Catalytic cyclopropanation of stereoisomeric 1,3-dichloropropenes with methyl diazoacetate

被引：0
|
作者：
Shiriazdanova, A. R. [1 ]
Sultanova, R. M. [2 ]
Spirikhin, L. V. [2 ]
Zlotskii, S. S. [1 ]
机构：
[1] Ufa State Petr Tech Univ, Ufa 450062, Russia
[2] Russian Acad Sci, Ufa Sci Ctr, Inst Organ Chem, Ufa 450001, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2012年 / 82卷 / 07期
关键词：
Acac; Chloromethyl; Methoxycarbonyl; Cyclopropane Ring; Allyl Chloride;
D O I：
10.1134/S1070363212070067
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The catalytic cyclopropanation of cis- and trans-1,3-dichlorpropenes with methyl diazoacetate in the presence of a copper catalyst was studied. The products composition and ratio were shown to depend on the spatial structure of 1,3-dichloropropene.
引用
收藏
页码：1224 / 1227
页数：4
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