Radiation chemistry of polysaccharides: 4. Free-radical mechanisms of formaldehyde formation

被引：3
|
作者：
Sharpatyi, VA [1 ]
机构：
[1] Russian Acad Sci, Emanuel Inst Biochem Phys, Moscow 119991, Russia
来源：
HIGH ENERGY CHEMISTRY | 2006年 / 40卷 / 01期
关键词：
D O I：
10.1134/S0018143906010036
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Based on an analysis of author's experimental results and published data on the radiolysis of polysaccharides, three main reaction paths of CH2O fort-nation related to the transformations of primary radicals with impaired electrons on C1, C5, and C6 atoms were revealed. The formaldehyde molecule was formed in the primary event of C5 radical conversion or through the steps of formyl radical fort-nation in the other two cases.
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页码：15 / 17
页数：3
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