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- [44] Retention of structural cores in the synthesis of high-nuclearity polyoxoalkoxomolybdate clusters encapsulating [Na(H2O)3](+) and [MoO3] moieties. Hydrothermal syntheses and structures of (NH4)(7)[NaH12Mo16O52]center dot 4H(2)O and (Me(3)NH)(4)K-2[H14Mo16O52]center dot 8H(2)O and their structural relationships to the class of superclusters [XH(n)Mo(42)O(109){(OCH2)(3)CR}(7)](m-) (X=Na(H2O)(3)(+): n=13, m=9; n=15, m=7. X=MoO3: n=14, m=9; n=13, m=10) INORGANIC CHEMISTRY, 1996, 35 (07) : 1880 - 1901