Bis{2-methoxy-6-[(4-methylphenyl)-iminiomethyl]phenolato-κO1}bis(thiocyanato-κN) zinc(II)

被引：3
|
作者：
Li, Hua-Qiong
Xian, Hui-Duo
Liu, Jian-Feng
Zhao, Guo-Liang [1 ]
机构：
[1] Zhejiang Normal Univ, Inst Phys Chem, Zhejiang Key Lab React Chem Solid Surfaces, Jinhua 321004, Zhejiang, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词：
D O I：
10.1107/S1600536808035368
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The Schiff base 2-[(4-methylphenyl)iminomethyl]-6-methoxy-phenol (HL) forms a complex with a Zn2+ atom and two independent thiocyanate ions, [Zn(NCS)(2)(C15H15NO2)(2)], in which two phenolate O atoms the two independent Schiff base ligands are coordinated to thee Zn2+ atom. The protonated imine N atoms are involved in an intramolecular hydrogen bond with the phenoxide group. The Zn atom is also coordinated by two N atoms of two thiocyanate ligands. The coordination environment of the Zn atom is distorted-tetrahedral.
引用
收藏
页码：M1495 / U126
页数：11
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