A trans-platinum(II) complex as a single-molecule insulator

被引：0
|
作者：
Mayor, M [1 ]
von Hänisch, C [1 ]
Weber, HB [1 ]
Reichert, J [1 ]
Beckmann, D [1 ]
机构：
[1] Forschungszentrum Karlsruhe GmbH, Inst Nanotechnol, D-76021 Karlsruhe, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2002年 / 41卷 / 07期
关键词：
electron transport; insulators; molecular electronics; platinum; single-molecule studies;
D O I：
10.1002/1521-3773(20020402)41:7<1183::AID-ANIE1183>3.0.CO;2-Z
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A further component for molecular electronics: A single molecule insulator is realized by immobilizing a platinum(II) complex between two gold electrodes (see picture). The current/voltage characteristics of the setup shows the typical behavior of an insulator with a tunnel barrier height of 2.5 eV.
引用
收藏
页码：1183 / +
页数：5
相关论文
共 50 条
  • [41] Single-Molecule Electroluminescence of a Phosphorescent Organometallic Complex
    Sekiguchi, Yasuhiro
    Habuchi, Satoshi
    Vacha, Martin
    CHEMPHYSCHEM, 2009, 10 (08) : 1195 - 1198
  • [42] Trans-Platinum/Thiazole Complex Interferes with Sp1 Zinc-Finger Protein
    Chen, Siming
    Xu, Dechen
    Jiang, Huan
    Xi, Zhaoyong
    Zhu, Pingping
    Liu, Yangzhong
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (49) : 12258 - 12262
  • [43] Single-Molecule Study of Human Topoisomerase II
    Seol, Yeonee
    Gentry, Amanda C.
    Osheroff, Neil
    Neuman, Keir C.
    BIOPHYSICAL JOURNAL, 2010, 98 (03) : 660A - 660A
  • [44] A nonanuclear iron(II) single-molecule magnet
    Boudalis, AK
    Donnadieu, B
    Nastopoulos, V
    Clemente-Juan, JM
    Mari, A
    Sanakis, Y
    Tuchagues, JP
    Perlepes, SP
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (17) : 2266 - 2270
  • [45] Unfolded Protein Response is Involved in Trans-Platinum (II) Complex-Induced Apoptosis in Prostate Cancer Cells via ROS Accumulation
    Karakas, Didem
    Cevatemre, Buse
    Oral, Arzu Y.
    Yilmaz, Veysel T.
    Ulukaya, Engin
    ANTI-CANCER AGENTS IN MEDICINAL CHEMISTRY, 2019, 19 (09) : 1184 - 1195
  • [46] ALKYNYL CHLORIDE EXCHANGE BETWEEN TRANS-PLATINUM(II) AND TRANS-PALLADIUM(II) CHLORIDES AND ALKYNYLSTANNANES - CRYSTAL-STRUCTURE OF TRANS-[BIS(1-PROPYNYL)-BIS(TRIETHYLPHOSPHINE)PLATINUM(II)]
    SEBALD, A
    STADER, C
    WRACKMEYER, B
    BENSCH, W
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 311 (1-2) : 233 - 242
  • [47] A Trigonal Prismatic Mononuclear Cobalt(II) Complex Showing Single-Molecule Magnet Behavior
    Novikov, Valentin V.
    Pavlov, Alexander A.
    Nelyubina, Yulia V.
    Boulon, Marie-Emmanuelle
    Varzatski, Oleg A.
    Voloshin, Yan Z.
    Winpenny, Richard E. P.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (31) : 9792 - 9795
  • [48] Verification of Single-Molecule Imaging and Single-Molecule Measurements
    Ishijima, Akihiko
    Fukuoka, Hajime
    Inoue, Yuichi
    JOURNAL OF ROBOTICS AND MECHATRONICS, 2010, 22 (05) : 568 - 578
  • [49] EFFECTS OF CIS-PLATINUM AND TRANS-PLATINUM COMPLEXES ON RNA-TRANSCRIPTION
    MILLER, D
    MINAHAN, DMA
    FRIEDMAN, ME
    KOHL, HH
    MCAULIFFE, CA
    CHEMICO-BIOLOGICAL INTERACTIONS, 1983, 44 (03) : 311 - 316
  • [50] Combining single-molecule manipulation and single-molecule detection
    Cordova, Juan Carlos
    Das, Dibyendu Kumar
    Manning, Harris W.
    Lang, Matthew J.
    CURRENT OPINION IN STRUCTURAL BIOLOGY, 2014, 28 : 142 - 148
12345