Gold(III) Olefin Complexes

被引：71

作者：

Savjani, Nicky ^{[1
]}

Rosca, Dragos-Adrian ^{[1
]}

Schormann, Mark ^{[1
]}

Bochmann, Manfred ^{[1
]}

机构：

[1] Univ E Anglia, Wolfson Mat & Catalysis Ctr, Sch Chem, Norwich NR4 7TJ, Norfolk, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 03期

关键词：

aurophilic bonds; coordination chemistry; ethylene; gold; homogeneous catalysis; NUCLEAR-MAGNETIC-RESONANCE; GOLD CATALYSIS; HOMOGENEOUS CATALYSIS; CRYSTAL-STRUCTURE; ORGANIC TRANSFORMATIONS; AUROPHILIC INTERACTIONS; MOLECULAR STRUCTURE; ZEISES SALT; HYDROGENATION; ETHYLENE;

D O I：

10.1002/anie.201208356

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Zeise's salt gets company: 185 years after the report of the well-known platinum(II) ethylene compound, examples of isolable olefin complexes of its isoelectronic neighbor in the periodic table, gold(III), have been prepared (see picture). The complexes are very susceptible towards nucleophilic attack; there is also structural evidence for AuIII-Ag interactions. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：874 / 877

页数：4

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