Coupling of chrysanthemum-shaped cobalt hydroxide and nitrogen-doped carbon dots for high-performance hybrid supercapacitors

被引:3
|
作者
Chen, Zihan [1 ,4 ]
Zheng, Weijie [2 ,3 ,4 ]
Zhang, Xiang [2 ,3 ,4 ]
Zheng, Yuying [1 ,4 ]
机构
[1] Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350116, Peoples R China
[2] Chinese Acad Sci, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
[3] Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, Key Lab Optoelect Mat Chem & Phys,State Key Lab St, Fuzhou 350002, Fujian, Peoples R China
[4] Fuzhou Univ, Coll Chem Engn, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Peoples R China
关键词
Carbon dots; Supercapacitors; Cobalt hydroxide; Graphene; Storage; METAL-ORGANIC FRAMEWORK; QUANTUM DOTS; WATER OXIDATION; CO; ELECTRODE; ELECTROCATALYST; EVOLUTION;
D O I
10.1016/j.jelechem.2022.116666
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Cobalt hydroxide is expecting electrode material for high-performance supercapacitors, however, it is still a challenge to improve its lack of transmission track and active sites. An effective method to improve the elec-trochemistry performance of cobalt hydroxide is to couple it with graphene quantum dots. Herein, we report the preparation of Cobalt hydroxide/N doped graphene quantum dots (Co(OH)2/NQDs) composites and study the electrochemistry performance of Co(OH)2/NQDs composites as supercapacitors electrode materials. Benefit from the strong coupling between NQDs and Co(OH)2 creates new electron transfer channels (Co-N). The hybrid supercapacitor device based on Co(OH)2/NQDs composite and GA shows a high energy density of about 33.6 Wh kg-1 at a power density of 800 Wk g-1, and it retains about 137% specific capacitances after 8000 cycle test. Due to the negative potential of NQDS, it can generate an electrostatic reaction with Co2+, which can stabilize cobalt hydroxide after long cycles.
引用
收藏
页数:10
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