Transition metal-containing macromolecules: En route to new functional materials

被引:97
|
作者
Abd-El-Aziz, Alaa S. [1 ,2 ]
Strohm, Elizabeth A. [2 ]
机构
[1] Univ Prince Edward Isl, Dept Chem, Charlottetown, PE C1A 4P3, Canada
[2] Univ British Columbia, Dept Chem, Kelowna, BC V1V 1V7, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
Organometallic polymers; Coordination polymers; Metallocene-based systems; RING-OPENING POLYMERIZATION; LIVING ANIONIC-POLYMERIZATION; CONTAINING POLYMERS; ORGANOMETALLIC POLYMERS; COORDINATION POLYMERS; BLOCK-COPOLYMERS; SUPRAMOLECULAR ISOMERISM; DENDRITIC MACROMOLECULES; MOLECULAR ARCHITECTURE; CARBOSILANE DENDRIMERS;
D O I
10.1016/j.polymer.2012.08.024
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Recent development in the field of organometallic and coordination polymers based on transition metals, particularly the methods and degree of polymerization, the nature of bonding present, and the type of metal moiety, has become an area of ever-growing interest. Metal-containing polymers have catalytic, magnetic, optical, electrical, and electrochemical properties which allow for a variety of applications. This review will mainly shed light on the past five years of research in organometallic and coordination polymers containing transition metals, focusing on the synthetic methodologies, structural properties, and applications. (c) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:4879 / 4921
页数:43
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