Synthesis and conformational analysis of 3,5,7-triaryl-1,3,5,7-oxatriazocanes

被引：0
|
作者：
Kakanejadifard, Ali [1 ]
Zabardasti, Abedin [1 ]
Kakanejadifard, Hadis [1 ]
机构：
[1] Lorestan Univ, Fac Sci, Dept Chem, Khorramabad, Iran
来源：
ASIAN JOURNAL OF CHEMISTRY | 2008年 / 20卷 / 06期
关键词：
3,5,7-triaryl-1,3,5,7-oxatriazocane; ab initio calculation; conformational analysis;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
By condensation of arylamines and formaldehyde in equimolar ratio, using formic acid as catalyst and acetonitrile as a solvent at room temperature, 3,5,7-triaryl-1,3,5,7-oxatriazocanes (2-5) were formed. The composition and structural formula of all compounds were confirmed by elemental analysis, IR, MS and NMR spectroscopy methods. Theoretical calculation were used for conformational analysis of 3,5,7-tri(4-chlorophenyl)-1,3,5,7-oxatriazocane in the gas phase at HF/3-21 + g(d.p) level of computational study. Results show that stability of various structures are in the order: crown > saddle > boat chair family.
引用
收藏
页码：4706 / 4712
页数：7
相关论文
共 50 条
  • [31] REACTIONS OF HETEROCYCLIC CATIONS WITH N-CONTAINING NUCLEOPHILES .10. SYNTHESIS OF 3,5,7-TRIARYL-1,2-OXAZEPINIUM PERCHLORATES BY THE REACTION OF 2,4,6-TRIARYLPYRILIUM SALTS WITH NITRONS AND SUBSTITUTED HYDROXYLAMINES
    ZVEZDINA, EA
    GOLYANSKAYA, OM
    ANDREYEVA, IM
    POPOVA, AN
    MEDYANTSEVA, YA
    DOROFEYENKO, GN
    KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1982, (04): : 457 - 460
  • [32] DETERMINATION OF 1,3,5,7-TETRANITRO-1,3,5,7-TETRAAZACYCLOOCTANE IN MICROGRAM QUANTITIES
    HOFFSOMMER, JC
    GLOVER, DJ
    KUBOSE, DA
    JOURNAL OF CHROMATOGRAPHY, 1975, 103 (01): : 182 - 185
  • [33] Thermodynamics of polymethylhydrosiloxane based on 1,3,5,7-tetramethyl-1,3,5,7-tetrahydrocyclotetrasiloxane
    Smirnova, N. N.
    Tsvetkova, L. Ya.
    Lebedev, B. V.
    Zavin, B. G.
    Kotov, V. M.
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2007, 89 (01) : 217 - 222
  • [34] Synthesis and Characterization of an Eight-Membered Heterocyclic 1,3,5,7-Tetra(3-pyridyl)-1,3,5,7-tetrazacyclooctane
    Li, Li
    Dai, Guo-Liang
    Zhu, Xue Hua
    Yu, Lei
    Li, Hai Yan
    SYNOPEN, 2023, 07 (04): : 486 - 490
  • [35] CRYSTALLINE FORM OF 1,3,5,7-TETRANITRO-1,3,5,7-TETRAZACYCLOOCTANE (HMX)
    BEDARD, M
    MYERS, JL
    WRIGHT, GF
    HUBER, H
    CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1962, 40 (12): : 2278 - &
  • [36] Thermodynamics of polymethylhydrosiloxane based on 1,3,5,7-tetramethyl-1,3,5,7-tetrahydrocyclotetrasiloxane
    N. N. Smirnova
    L. Ya. Tsvetkova
    B. V. Lebedev
    B. G. Zavin
    V. M. Kotov
    Journal of Thermal Analysis and Calorimetry, 2007, 89 : 217 - 222
  • [37] Kinetics of the β→δ structural reorganization in 1,3,5,7-tetranitrooctahydro-1,3,5,7-tetrazocine
    V. V. Zakharov
    B. L. Korsunskii
    Russian Chemical Bulletin, 2011, 60 : 1436 - 1439
  • [38] UNSATURATED HETEROCHAINS .2. 1-OXA-3,5,7-TRIAZA-1,3,5,7-OCTATETRAENES - SYNTHESES AND STRUCTURES
    BUHMANN, M
    MOLLER, MH
    RODEWALD, U
    WURTHWEIN, EU
    CHEMISCHE BERICHTE-RECUEIL, 1993, 126 (11): : 2467 - 2476
  • [39] Polymorphism and White Light Emission of 1-Bromo-3,5,7-triphenyladamantane Compared with 1,3,5,7-Tetraphenyladamantane
    Gowrisankar, Saravanan
    Fokin, Andrey A.
    Becker, Jonathan
    Mathew, Neeshma
    Guenne, Joern Schmedt Auf Der
    Schreiner, Peter R.
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2024, 27 (23)
  • [40] Kinetics of the β→δ structural reorganization in 1,3,5,7-tetranitrooctahydro-1,3,5,7-tetrazocine
    Zakharov, V. V.
    Korsunskii, B. L.
    RUSSIAN CHEMICAL BULLETIN, 2011, 60 (07) : 1436 - 1439
12345