The characterization of latex particles prepared by pulsed electron beam induced emulsion polymerization

被引：1
|
作者：
Xu, Yongfei [1 ]
Wang, Mozhen [1 ]
Ge, Xuewu [1 ]
机构：
[1] Univ Sci & Technol China, Dept Polymer Sci & Engn, CAS Key Lab Soft Matter Chem, Hefei 230026, Anhui, Peoples R China
来源：
RADIATION PHYSICS AND CHEMISTRY | 2012年 / 81卷 / 10期
基金：
中国国家自然科学基金;
关键词：
High energy pulsed electron beam; Emulsion polymerization; Styrene; Methyl methacrylate; Porous structure; FREE-RADICAL POLYMERIZATION; FLASH-INITIATED POLYMERIZATION; INDIVIDUAL KINETIC CONSTANTS; EVALUATED RATE COEFFICIENTS; PROPAGATION; TOOL; STYRENE;
D O I：
10.1016/j.radphyschem.2012.05.001
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The emulsion polymerization of styrene (St) and methyl methacrylate (MMA) induced by 10 MeV pulsed electron beams (PEB) was investigated. The monomer conversion of MMA and St was found to be very low so that the final prepared poly(methyl methacrylate) (P(MMA)) and polystyrene (PS) latex particles exhibit porous structures, as verified by TEM and SEM observations. The results of dynamic light scattering (DLS) and gel permeation chromatography (GPC) showed that both the particle size and the molecular weight of PS and PMMA latexes decrease with the increase of the absorbed dose. However, the molecular weights and the particle sizes of the PS and PMMA latexes change differently with the irradiation time. This work indicated that emulsion polymerization induced by high energy electron beam has an advantage over that induced by gamma-ray or chemical initiators in the preparation of latex with a low molecular weight and porous structure. (c) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1634 / 1638
页数：5
相关论文
共 50 条
  • [21] Preparation and Characterization of Crosslinking Polyacrylate Latex Prepared by Soap-Free Emulsion Polymerization
    Chen, Lijun
    Gong, Zheqing
    POLYMER SCIENCE SERIES B, 2023, 65 (06) : 836 - 841
  • [22] Synthesis and characterization of Al(OH)3/polystyrene nanocomposite latex particles by emulsion polymerization
    Park, Eun Ju
    Heo, Hoon
    Lim, Kwon Taek
    MACROMOLECULAR SYMPOSIA, 2007, 249 : 247 - 250
  • [23] Poly (styrene/hydroxypropyl methylcellulose phthalate) latex particles prepared by resin-fortified emulsion polymerization
    Lee, Jung Min
    Cho, Ji Eun
    Kim, Jung Hyun
    Cho, Heui Kyoung
    Cheong, In Woo
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2007, 307 (1-3) : 35 - 44
  • [24] Morphological evolution of latex particles for VAc/BA core/shell prepared by two stage emulsion polymerization
    Zhao, K
    Sun, PQ
    Liu, DZ
    ACTA POLYMERICA SINICA, 2002, (02) : 257 - 260
  • [25] Polar Gradient Latex Particles with Hydrophilic Core and Hydrophobic Shell Prepared via Multistep Emulsion Polymerization
    Deng Wei
    Zhang Mengjun
    Ji Wenjiao
    Kan Chengyou
    CHINESE JOURNAL OF CHEMISTRY, 2011, 29 (04) : 853 - 856
  • [26] Morphology of P(BA-St-DAAM) latex particles prepared by seeded-emulsion polymerization
    Li, HP
    Kan, CY
    Du, Y
    Liu, DS
    POLYMERS FOR ADVANCED TECHNOLOGIES, 2003, 14 (3-5) : 212 - 215
  • [27] Absorption of free radicals into latex particles in the reactions of emulsion polymerization
    Lukhovitskij, V.I.
    Polikarpov, V.V.
    Krylova, L.A.
    Vysokomolekularnye Soedineniya. Ser.A Ser.B Ser.C - Kratkie Soobshcheniya, 1993, 35 (05): : 499 - 503
  • [28] Modeling the emulsion polymerization of amino-functionalized latex particles
    Ramos, J
    Forcada, J
    POLYMER, 2006, 47 (04) : 1405 - 1413
  • [29] EMULSION POLYMERIZATION .6. CONCENTRATION OF MONOMERS IN LATEX PARTICLES
    GARDON, JL
    JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1968, 6 (10PA): : 2859 - &
  • [30] Hybrid latex particles preparation with seeded semibatch emulsion polymerization
    Zhang Zhenqian
    Xie Bo
    Wang Pei
    Yuan Ninyyi
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2015, 482 : 422 - 430
12345