Unexpected dual orbital effects in radical addition reactions involving acyl, silyl and related radicals

被引：26
|
作者：
Schiesser, CH [1 ]
Matsubara, H
Ritsner, I
Wille, U
机构：
[1] Univ Melbourne, Sch Chem, Melbourne, Vic 3010, Australia
[2] Univ Melbourne, Bio21 Mol Sci & Biotechnol Inst, Melbourne, Vic, Australia
[3] Osaka Prefecture Univ, Grad Sch Sci, Dept Chem, Sakai, Osaka 5998531, Japan
来源：
CHEMICAL COMMUNICATIONS | 2006年 / 10期
关键词：
D O I：
10.1039/b515330a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Molecular orbital calculations reveal that acyl and silyl radicals add to numerous types of pi-systems through simultaneous SOMO-LUMO and LUMO-HOMO interactions of the radical with the radicalophile respectively.
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页码：1067 / 1069
页数：3
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