Tandem Hydroformylation/Hydrogenation of Alkenes to Normal Alcohols Using Rh/Ru Dual Catalyst or Ru Single Component Catalyst

被引：112
|
作者：
Takahashi, Kohei [1 ]
Yamashita, Makoto [1 ]
Nozaki, Kyoko [1 ]
机构：
[1] Univ Tokyo, Grad Sch Engn, Dept Chem & Biotechnol, Bunkyo Ku, Tokyo 1138656, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 45期
基金：
日本学术振兴会;
关键词：
CARBON-DIOXIDE; BIPHASIC HYDROFORMYLATION; HYDROGENATION CATALYST; RUTHENIUM COMPLEXES; LINEAR ALCOHOLS; RHODIUM; LIGANDS; WATER; OLEFINS; HYDRIDE;
D O I：
10.1021/ja307998h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The catalyst system: for tandem hydroformylation/hydrogenation of terminal alkenes to the corresponding homologated normal alcohol was developed The reaction mechanism for the Rh/Ru dual catalyst was investigated by real-time IR monitoring experiments and P-31 NMR spectroscopy, which proved the mutual orthogonality of Rh-catalyzed hidroformylation and Ru-catalyzed hydrogenation. Detailed investigation about Ru-catalyzed hydrogenation of undecanal under H-2/CO pressure clarified different kinetics from the hydrogenation under H-2 and gave a clue to design more active hydrogenation catalysts under H-2/CO atmosphere. The solely Ru-catalyzed normal selective hydroformylation/hydrogenation is also reported.
引用
收藏
页码：18746 / 18757
页数：12
相关论文
共 50 条
  • [21] Reaction Kinetics of Vanillin Hydrogenation in Aqueous Solutions Using a Ru/C Catalyst
    Bindwal, Ankush B.
    Vaidya, Prakash D.
    ENERGY & FUELS, 2014, 28 (05) : 3357 - 3362
  • [22] Hydrogenation of methyl methacrylate under mild conditions using biosynthesis Ru catalyst
    Zhou, Hongling
    Huang, Yangqiang
    Cheng, Youwei
    Wang, Lijun
    Li, Xi
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2017, 47 : 221 - 227
  • [23] Highly Selective Hydrogenation of Tetralin to cis-Decalin Using Ru Catalyst
    Wang, Qian
    Hou, Yunchan
    Zhao, Haiyang
    Li, Yuqing
    Jia, Aijing
    CHEMISTRYSELECT, 2019, 4 (19): : 5796 - 5798
  • [24] Optimum process parameters for hydrogenation of acrylonitrile-butadiene rubber using Rh-Ru bimetallic complex catalyst
    Yao, Ming
    Zhou, Shuqin
    Xu, Ruiqing
    Yue, Dongmei
    Hsu, Kueihsien
    Zhong, Yuzhen
    Huagong Xuebao/Journal of Chemical Industry and Engineering (China), 2002, 53 (06): : 607 - 610
  • [25] Single-atom Ru catalyst for selective synthesis of 3-pentanone via ethylene hydroformylation
    Qin, Tingting
    Dang, Yaru
    Lin, Tiejun
    Mei, Bingbao
    Wu, Bo
    Li, Xiao
    Li, Shenggang
    Jiang, Zheng
    Tang, Zhiyong
    Zhong, Liangshu
    Sun, Yuhan
    GREEN CHEMISTRY, 2021, 23 (22) : 9038 - 9047
  • [26] Preparation of hydrogenated nitrile rubber using Rh-Ru bimetallic biligand catalyst
    Zhou, Shu-Qin
    Yao, Ming
    Xu, Rui-Qing
    Beijing Huagong Daxue Xuebao(Ziran Kexueban)/Journal of Beijing University of Chemical Technology, 2002, 29 (04):
  • [27] Asymmetric hydrogenation using a covalently immobilized Ru-BINOL-AP@MSNs catalyst
    Lakhani, Pratikkumar
    Modi, Chetan K.
    NEW JOURNAL OF CHEMISTRY, 2023, 47 (18) : 8767 - 8775
  • [28] Studies on some hydrogenation reactions using Pd(II) and Ru(III) supported catalyst
    Patel, Heemanshu
    Joshi, Rikesh
    Chudasama, Uma
    JOURNAL OF SCIENTIFIC & INDUSTRIAL RESEARCH, 2009, 68 (09): : 794 - 799
  • [29] Tunable HMF hydrogenation to furan diols in a flow reactor using Ru/C as catalyst
    Fulignati, Sara
    Antonetti, Claudia
    Wilbers, Erwin
    Licursi, Domenico
    Heeres, Hero Jan
    Galletti, Anna Maria Raspolli
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2021, 100 (100) : 390.e1 - 390.e9
  • [30] Insight into the hydrogenation of pure and crude HMF to furan diols using Ru/C as catalyst
    Fulignati, Sara
    Antonetti, Claudia
    Licursi, Domenico
    Pieraccioni, Matteo
    Wilbers, Erwin
    Heeres, Hero Jan
    Galletti, Anna Maria Raspolli
    APPLIED CATALYSIS A-GENERAL, 2019, 578 : 122 - 133
12345