Topochemical Oxidation of Perovskite KCoF3 to a K2PtCl6 Structure-Type Oxyfluoride

被引：8

作者：

Nagarajan, Rajamani ^{[1
]}

Ahmad, Shahzad ^{[1
]}

Singh, Poonam ^{[1
]}

机构：

[1] Univ Delhi, Dept Chem, Mat Chem Grp, Delhi 110007, India

来源：

INORGANIC CHEMISTRY | 2015年 / 54卷 / 21期

关键词：

SINGLE-SOURCE PRECURSOR; PHOTOCATALYTIC PROPERTIES; TETRAVALENT COBALT; OXIDE-FLUORIDES; TEMPERATURE; NANOCRYSTALS; CHEMISTRY; SPECTRA; ANION;

D O I：

10.1021/acs.inorgchem.5b01694

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Oxyfluoride, K(2)CoOF4 with K2PtCl6 structure, has been stabilized from a perovskite-based KCoF3 complex by a simple oxidative anion insertion topochemical reaction. Similar structural transformations have been observed for Ni- and Mn-containing systems. The generation of such unusual compounds, by soft chemical methods, strengthens the efforts toward materials discovery

引用

页码：10105 / 10107

页数：3

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