Topochemical Oxidation of Perovskite KCoF3 to a K2PtCl6 Structure-Type Oxyfluoride

被引：8
|
作者：
Nagarajan, Rajamani [1 ]
Ahmad, Shahzad [1 ]
Singh, Poonam [1 ]
机构：
[1] Univ Delhi, Dept Chem, Mat Chem Grp, Delhi 110007, India
来源：
INORGANIC CHEMISTRY | 2015年 / 54卷 / 21期
关键词：
SINGLE-SOURCE PRECURSOR; PHOTOCATALYTIC PROPERTIES; TETRAVALENT COBALT; OXIDE-FLUORIDES; TEMPERATURE; NANOCRYSTALS; CHEMISTRY; SPECTRA; ANION;
D O I：
10.1021/acs.inorgchem.5b01694
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Oxyfluoride, K(2)CoOF4 with K2PtCl6 structure, has been stabilized from a perovskite-based KCoF3 complex by a simple oxidative anion insertion topochemical reaction. Similar structural transformations have been observed for Ni- and Mn-containing systems. The generation of such unusual compounds, by soft chemical methods, strengthens the efforts toward materials discovery
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页码：10105 / 10107
页数：3
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