The ups and downs of C-H hydrogen bonds

被引:87
|
作者
Jeffrey, GA [1 ]
机构
[1] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15260 USA
关键词
C-H hydrogen bonds; controversial history; non-directional H-bonds; biological significance;
D O I
10.1016/S0022-2860(99)00049-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
C-H ... O hydrogen bonding has been known for more than sixty years. At one time it was a controversial subject. For the past sixteen years, its credibility has steadily increased until now it is very fashionable. Weak C-H ... O interactions appear to be non-directional. Does this disqualify them as hydrogen bonds? (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:293 / 298
页数:6
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