Catalysts for producing methanol and isobutanol mixtures from synthesis gas

被引:29
|
作者
Apesteguia, CR [1 ]
DeRites, B [1 ]
Miseo, S [1 ]
Soled, S [1 ]
机构
[1] EXXON RES & ENGN CO,CORP RES SCI LABS,ANNANDALE,NJ 08801
关键词
isobutanol synthesis; synthesis gas; Cu/Ce(Y)/Mg catalysts;
D O I
10.1023/A:1018987900456
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The coproduction of methanol and isobutanol from synthesis gas over new catalysts based on coprecipitated solid solutions of alkaline earth oxides and rare earth oxides promoted by copper has been investigated. It is shown that the catalysts are active and selective to isoalcohol synthesis at temperatures and pressures lower than those required by prior art catalysts.
引用
收藏
页码:1 / 5
页数:5
相关论文
共 50 条
  • [21] Application of the thermodynamic method to developing the process of producing methanol and dimethyl ether from synthesis gas
    M. Kh. Sosna
    Yu. A. Sokolinskii
    N. Yu. Shovkoplyas
    E. V. Korolev
    Theoretical Foundations of Chemical Engineering, 2007, 41 : 809 - 815
  • [22] Application of the thermodynamic method to developing the process of producing methanol and dimethyl ether from synthesis gas
    Sosna, M. Kh.
    Sokollinskii, Yu. A.
    Shovkoplyas, N. Yu.
    Korolev, E. V.
    THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING, 2007, 41 (06) : 809 - 815
  • [23] SYNTHESIS OF HYDROCARBONS FROM METHANOL WITH COBALT CATALYSTS
    BLANCHARD, M
    MAKAMBO, L
    VANHOVE, D
    NOUVEAU JOURNAL DE CHIMIE-NEW JOURNAL OF CHEMISTRY, 1982, 6 (10): : 459 - 460
  • [24] The activity of Fischer-Tropsch catalysts in hydrocarbon synthesis from dilute gas mixtures
    Vytnova, LA
    Kliger, GA
    Bogolepova, EI
    Shuikin, AN
    Kurkin, VI
    Kuz'min, AE
    Slivinskii, EV
    Zaikin, VG
    PETROLEUM CHEMISTRY, 2001, 41 (03) : 182 - 189
  • [25] Isobutanol synthesis from syngas
    Falter, W
    Finkeldei, CH
    Jaeger, B
    Keim, W
    Verkerk, KAN
    NATURAL GAS CONVERSION V, 1998, 119 : 465 - 471
  • [26] Methanol decomposition to synthesis gas over supported Pd catalysts prepared from hydrotalcite precursors
    Shishido, T
    Sameshima, H
    Takehira, K
    TOPICS IN CATALYSIS, 2003, 22 (3-4) : 261 - 269
  • [27] Synthesis of methanol and isobutanol by CO hydrogenation over Pd-modified K/MnOx-ZrO2 catalysts
    He, DP
    Ding, YJ
    CHINESE JOURNAL OF CATALYSIS, 2005, 26 (11) : 961 - 964
  • [28] METHANOL FROM SYNTHESIS GAS OVER IRON-RICH IRON IRIDIUM ON SILICA CATALYSTS
    KONINGSBERGER, DC
    BORGMANS, CPJH
    VANELDEREN, AMJ
    KIP, BJ
    NIEMANTSVERDRIET, JW
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (12) : 892 - 894
  • [29] Methanol Decomposition to Synthesis Gas Over Supported Pd Catalysts Prepared from Hydrotalcite Precursors
    T. Shishido
    H. Sameshima
    K. Takehira
    Topics in Catalysis, 2003, 22 : 261 - 269
  • [30] Molecular interactions in the mixtures of 2-chloroaniline with equimolar mixture of methanol and isopropanol/isobutanol
    Kumar, D. Sravana
    Srikanth, K.
    Rao, D. Krishna
    JOURNAL OF MOLECULAR LIQUIDS, 2007, 136 (1-2) : 90 - 93