Design, Synthesis, Characterization, and Catalytic Properties of a Large-Pore Metal-Organic Framework Possessing Single-Site Vanadyl(monocatecholate) Moieties

被引：40
|
作者：
Nguyen, Huong Giang T.
Weston, Mitchell H.
Sarjeant, Amy A.
Gardner, Daniel M.
An, Zhi
Carmieli, Raanan
Wasielewski, Michael R.
Farha, Omar K. [1 ]
Hupp, Joseph T.
Nguyen, SonBinh T.
机构：
[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
来源：
CRYSTAL GROWTH & DESIGN | 2013年 / 13卷 / 08期
关键词：
SELECTIVE OXIDATION; MOF; INTERPENETRATION; PROTECTION; EXCHANGE; CRYSTAL; MIL-101; SOLIDS;
D O I：
10.1021/cg400500t
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Through a combination of protecting groups, postsynthesis deprotection, and postsynthesis metallation, a homogeneously inaccessible, single-site vanadyl-(monocatecholate) moiety can be incorporated into the dipyridyl struts of a Zn-based, pillared paddlewheel MOF. The resulting MOF, which has large pores, exhibits catalytic activity in the benzylic oxidation of tetralin in the presence of tert-butylhydroperoxide.
引用
收藏
页码：3528 / 3534
页数：7
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