Effect of Metal-modified Carbon Catalysts on Fast Pyrolysis of Jatropha Waste

被引:4
|
作者
Murata, Kazuhisa [1 ,3 ]
Sricharoenchaikul, Viboon [2 ,3 ]
Liu, Yanyong [1 ]
Inaba, Megumu [1 ]
Takahara, Isao [1 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, Energy Technol Res Inst, Higashi Ku, Tsukuba, Ibaraki 3058565, Japan
[2] Natl Met & Mat Technol Ctr MTEC, Klongluang 12120, Pathumthani, Thailand
[3] Japan Sci & Technol Agcy JST, Chiyoda Ku, Tokyo 1020076, Japan
关键词
Fast pyrolysis; Jatropha waste; Activated carbon catalyst; Nickel-activated catalyst; Aromatic hydrocarbon; Pyrolysis GCMS; BIOMASS; OIL; CURCAS; FUELS; L;
D O I
10.1627/jpi.56.371
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Screening, synthesis, and testing of metal-modified carbon catalysts for fast pyrolysis of Jatropha waste were carried out using Pyro-GCMS (Py-GC/MS) and a quartz reactor. Our results suggest that activated carbon-based catalysts, especially those impregnated with Ni, are effective catalysts. The selectivity for aromatic and aliphatic hydrocarbons was 79.4 %, with relatively low amounts of oxygenated compounds or other unfavorable components. Using Ni/C catalyst in a quartz reactor, the selectivity for aromatic and aliphatic hydrocarbons was 64.1 %. Successive reaction through hydrogen migration over the metal-modified activated carbon catalyst surface could occur at 600 degrees C. Further improvements of catalyst activity and the reactor configuration may be required to produce liquid fuel commercially.
引用
收藏
页码:371 / 380
页数:10
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