Intense Blue Emission Phosphor BaCa2MgSi2O8: Eu2+ for Fluorescent Lamps

被引：12

作者：

Hou, Dejian ^{[1
]}

Chen, Wei ^{[2
]}

Ding, Xuemei ^{[1
]}

Liang, Hongbin ^{[1
]}

Zheng, Lirong ^{[3
]}

Zhang, Jing ^{[3
]}

机构：

[1] Sun Yat Sen Univ, MOE Lab Bioinorgan & Synthet Chem, KLGHEI Environm & Energy Chem, State Key Lab Optoelect Mat & Technol,Sch Chem &, Guangzhou 510275, Guangdong, Peoples R China

[2] KanHoo Ind Co Ltd, Jiangmen 529040, Peoples R China

[3] Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100039, Peoples R China

来源：

ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY | 2013年 / 2卷 / 04期

基金：

中国国家自然科学基金;

关键词：

THERMAL-STABILITY; ENERGY-TRANSFER; BAMGAL10O17-EU2+; LUMINESCENCE; VUV;

D O I：

10.1149/2.004305jss

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A series of Eu2+ doped BaCa2MgSi2O8 phosphors were prepared by a conventional solid state reaction route. Intense blue emission with a maximum at similar to 430 nm was observed under 254 nm UV light excitation. The oxidation state of Eu is confirmed by Eu-L-3 edge XANES. The luminescence spectra of optimal phosphor Ba0.97Eu0.03Ca2MgSi2O8 (BCMSO) was compared with that of commercial blue phosphor BaMgAl10O17:Eu2+ (BAM). The integrated emission intensity of BCMSO is higher than that of BAM under 254 nm excitation. White-light fluorescent lamps were fabricated using BCMSO and BAM as blue phosphors, respectively. The results indicate that the phosphor BCMSO may be suitable for application in tricolor lamps or other special fluorescent lamps. (C) 2013 The Electrochemical Society. All rights reserved.

引用

页码：R79 / R81

页数：3

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