Mild, Rapid, and Inexpensive Microwave-Assisted Synthesis of Allylic and Propargylic Esters

被引：3
|
作者：
Gill, Monica A. [1 ]
Manthorpe, Jeffrey M. [1 ]
机构：
[1] Carleton Univ, Dept Chem, Ottawa, ON K1S 5B6, Canada
来源：
SYNTHETIC COMMUNICATIONS | 2013年 / 43卷 / 10期
基金：
加拿大创新基金会; 加拿大自然科学与工程研究理事会;
关键词：
Allylic esters; esterification; microwave-assisted synthesis; mixed anhydride; propargylic esters; CLAISEN REARRANGEMENT; CARBOXYLIC ESTERS; DIHYDROXYLATION; REAGENTS;
D O I：
10.1080/00397911.2011.640970
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A variety of allylic and propargylic esters were rapidly prepared via microwave heating of their corresponding mixed anhydride derived from pivaloyl chloride. The reaction conditions were modified to account for the sterics of the alcohol and the electronics of the carboxylic acid. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) to view the free supplemental file.
引用
收藏
页码：1460 / 1468
页数：9
相关论文
共 50 条
  • [31] Microwave-assisted preparation of aryltetrazoleboronate esters
    Schulz, MJ
    Coats, SJ
    Hlasta, DJ
    ORGANIC LETTERS, 2004, 6 (19) : 3265 - 3268
  • [32] MICROWAVE-ASSISTED SYNTHESIS
    Gediz Erturk, Aliye
    Bekdemir, Yunus
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2014, 189 (02) : 285 - 292
  • [33] Microwave-assisted synthesis of deuterium labeled estrogen fatty acid esters
    Kiuru, PS
    Wähälä, K
    STEROIDS, 2006, 71 (01) : 54 - 60
  • [34] MICROWAVE-ASSISTED SYNTHESIS OF AROMATIC BIS-ESTERS IN LIQUID PHASE
    Zbancioc, Gheorghita N.
    Zbancioc, Ana Maria V.
    Mangalagiu, Ionel I.
    REVUE ROUMAINE DE CHIMIE, 2010, 55 (02) : 117 - +
  • [35] Rapid synthesis of hydroxyapatite nanopowders by a microwave-assisted combustion method
    Bovand, Nagmeh
    Rasouli, Sousan
    Mohammadi, Mohammad-Reza
    Bovand, Davood
    JOURNAL OF CERAMIC PROCESSING RESEARCH, 2012, 13 (03): : 221 - 225
  • [36] Rapid microwave-assisted solution-phase peptide synthesis
    Mahindra, Amit
    Sharma, Krishna K.
    Jain, Rahul
    TETRAHEDRON LETTERS, 2012, 53 (51) : 6931 - 6935
  • [37] Rapid synthesis of titania nanowires by microwave-assisted hydrothermal treatments
    Chung, Chin-Chun
    Chung, Tsair-Wang
    Yang, Thomas C. -K.
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2008, 47 (07) : 2301 - 2307
  • [38] Rapid microwave-assisted synthesis of polydextrose and identification of structure and function
    Wang, Haisong
    Shi, Yonghui
    Le, Guowei
    CARBOHYDRATE POLYMERS, 2014, 113 : 225 - 230
  • [39] Rapid synthesis of nanocrystalline ZnO by a microwave-assisted combustion method
    Nehru, L. C.
    Swaminathan, V.
    Sanjeeviraja, C.
    POWDER TECHNOLOGY, 2012, 226 : 29 - 33
  • [40] Rapid microwave-assisted synthesis of saponites and their use as oxidation catalysts
    Trujillano, R.
    Rico, E.
    Vicente, M. A.
    Rives, V.
    Ciuffi, K. J.
    Cestari, A.
    Gil, A.
    Korili, S. A.
    APPLIED CLAY SCIENCE, 2011, 53 (02) : 326 - 330
12345