Liquid phase oxidation of alkanes by tert-butyl hydroperoxide catalyzed by a manganese(III) pyridine amide complex

被引：0

作者：

Tembe, GL ^{[1
]}

Ganeshpure, PA ^{[1
]}

机构：

[1] Indian Petrochem Corp Ltd, Res Ctr, Vadodara 391346, India

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY | 1999年 / 38卷 / 05期

关键词：

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oxidation of alkanes by tert-butyl hydroperoxide in acetonitrile solution at room temperature has been performed in the presence of catalytic amounts of [Mn(bpc)OAc]MeOH, where bpc=4, 5-dichloro-1, 2-bis( pyridine- 2- carboxamido)benzene. Cyclohexane, adamantane, toluene, ethylbenzene and cumene give corresponding oxygenated products in moderate to high yields. A mechanism predominantly involving radical chain pathway is proposed.

引用

页码：611 / 613

页数：3

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