Palladium-Catalyzed Catellani Aminocyclopropanation Reactions with Vinyl Halides

被引：21

作者：

Khanna, Avinash ^{[1
]}

Premachandra, Ilandari Dewage Udara Anulal ^{[1
]}

Sung, Paul D. ^{[1
]}

Van Vranken, David L. ^{[1
]}

机构：

[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

ORGANIC LETTERS | 2013年 / 15卷 / 12期

基金：

美国国家科学基金会;

关键词：

CYCLOPROPANATION; ALKENES; REACTIVITY; DERIVATIVES; AMINATION; MECHANISM; PATHWAYS; KEY;

D O I：

10.1021/ol401383m

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium is shown to catalyze an Intramolecular aminocyclopropanation of norbornenes with aliphatic vinyl halides In good yields. The reaction tolerates a variety of amine substituents and gives good results with a variety of carbocyclic and oxabicyclic [2.2.1] alkene acceptors. Notably, stabilized enolate nucleophiles were also employed in cyclopropanation reactions.

引用

页码：3158 / 3161

页数：4

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