Functionalised η6-arene ruthenium complexes

被引：185

作者：

Therrien, Bruno ^{[1
]}

机构：

[1] Univ Neuchatel, Inst Chim, CH-2009 Neuchatel, Switzerland

来源：

COORDINATION CHEMISTRY REVIEWS | 2009年 / 253卷 / 3-4期

基金：

瑞士国家科学基金会;

关键词：

Arene ligands; Bio-organometallic chemistry; Clusters; Catalysis; Ruthenium; Piano-stool; P-C BOND; ASYMMETRIC TRANSFER HYDROGENATION; POLYMER-SUPPORTED CATALYSTS; X-RAY-DIFFRACTION; MOLECULAR-STRUCTURE; ARENE COMPLEXES; (ETA(6)-ETA(1)-C6H5CH2CH2PR2)RU(CH3)(2) R; RADICAL POLYMERIZATION; LIGANDS; CHEMISTRY;

D O I：

10.1016/j.ccr.2008.04.014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

eta(6)-Arene ruthenium complexes have been known for more than 30 years, and their chemistry has been extensively studied for Unfunctionalised arenes such as benzene, para-cymene and hexamethylbenzene. However, little is known about eta(6)-arene ruthenium complexes in which the arene ligand is not merely an aromatic hydrocarbon but contains chemical functions as substituents. This review gives an overview of functionalised eta(6)-arene ruthenium complexes, their syntheses and structures, as well as their intrinsic potential ranging from biological applications to applications as nano-materials. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：493 / 519

页数：27

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