Toward a Green Atom Economy: Development of a Sustainable Multicomponent Reaction

被引：25
|
作者：
Garbarino, Silvia [1 ]
Protti, Stefano [2 ]
Basso, Andrea [1 ]
机构：
[1] Univ Genoa, Bioorgan Chem Grp, Dept Chem & Ind Chem, I-16146 Genoa, Italy
[2] Univ Pavia, Dept Chem, PhotoGreen Lab, I-27100 Pavia, Italy
来源：
SYNTHESIS-STUTTGART | 2015年 / 47卷 / 16期
关键词：
multicomponent reactions; photochemistry; flow chemistry; green chemistry; diazo compounds; isocyanides; 3-COMPONENT REACTION; FLOW PHOTOCHEMISTRY; LIGHT; REARRANGEMENT; DESIGN;
D O I：
10.1055/s-0034-1380719
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The recently discovered photoinduced three-component reaction of diazo ketones, carboxylic acids, and isocyanides can be efficiently performed under continuous-flow conditions with consequential advantages in terms of selectivity and productivity. The investigation of the flow process and the determination of its sustainability are discussed in detail. This multicomponent reaction affords stereodefined captodative olefins, useful as synthons in organic chemistry.
引用
收藏
页码：2385 / 2390
页数：6
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