Synthesis of a new class of chiral β-mercaptoalcohols from amino acids

被引：0

作者：

Ge, JF ^{[1
]}

Shen, ZX ^{[1
]}

Zhang, LF ^{[1
]}

Zhang, YW ^{[1
]}

机构：

[1] Suzhou Univ, Dept Chem & Chem Engn, Suzhou 215006, Jiangsu, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2002年 / 20卷 / 01期

关键词：

beta-mercaptoalcohols; amino acids; synthesis;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The syntheses of three new optically active beta -mercaptoalcohols, (R)-1,1-diphenyl-2-mercapto-3-methyl-1-butanol, (R)-1,1-diphenyl-2-mercapto-4-methyl-1-pentanol, and (R)-1,1-diphen-2-mercapto-1-benzenepropanol from the corresponding amino adds am described. The enantiomeric excesses of these beta -mercaptoalcohols were determined by H-1 NMR as their (S)-mandeloyl derivatives.

引用

页码：79 / 84

页数：6

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