Rheological Characterization of Carbopol® Dispersions in Water and in Water/Glycerol Solutions

被引:109
|
作者
Varges, Priscilla R. [1 ]
Costa, Camila M. [1 ]
Fonseca, Bruno S. [1 ]
Naccache, Monica F. [1 ]
de Souza Mendes, Paulo R. [1 ]
机构
[1] Pontificia Univ Catolica RJ, Dept Mech Engn, Rua Marques de Sao Vicente 225, BR-22453900 Rio De Janeiro, RJ, Brazil
来源
FLUIDS | 2019年 / 4卷 / 01期
关键词
Carbopol; yield stress; thixotropy; YIELD-STRESS FLUIDS; FLOW PROPERTIES; OSCILLATORY SHEAR; GELS; INERTIA; POLYMER; SUSPENSIONS; INSTRUMENT; ELASTICITY; THIXOTROPY;
D O I
10.3390/fluids4010003
中图分类号
O3 [力学];
学科分类号
08 ; 0801 ;
摘要
The influence of the solvent type on the rheological properties of Carbopol (R) NF 980 dispersions in water and in water/glycerol solutions is investigated. The material formulation, preparation procedure, common experimental challenges and artifact sources are all addressed. Transient and steady-state experiments were performed. For both solvent types, a clearly thixotropic behavior occurs slightly above the yield stress, where the avalanche effect is observed. For larger stresses, thixotropy is always negligible. Among other findings, it is observed that, for a given Carbopol concentration, the dispersion in the more viscous solvent possesses a lower yield stress and moduli, a larger power-law index, and a longer time to reach steady state.
引用
收藏
页数:20
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