Graft Polymerization of Acrylonitrile-Sucrose and Determination of the Grafting Parameters

被引：0
|
作者：
Sadeghi, Mohammad [1 ]
Shafeie, Fatemeh [1 ]
Mohammadinasab, Esmat [1 ]
Soleimani, Fatemeh [1 ]
机构：
[1] Islamic Azad Univ, Arak Branch, Fac Sci, Dept Chem, Arak, Iran
来源：
ASIAN JOURNAL OF CHEMISTRY | 2013年 / 25卷 / 04期
关键词：
Sucrose; Acrylonitrile; Graft copolymerization; Ceric ammonium nitrate; METHYL ACRYLATE; SODIUM ALGINATE; COPOLYMERIZATION; STARCH; POLYMERS; OXIDATION; CELLULOSE;
D O I：
10.14233/ajchem.2013.13751
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Graft copolymerization of acrylonitrile onto sucrose was carried out under argon atmosphere in a homogeneous aqueous medium by using ceric ammonium nitrate as an initiator. A tentative mechanism is proposed to explain the generation of radicals and the initiation. The effect of the concentration of the initiator, monomer and polysaccharide as well as the reaction time and temperature on the graft copolymerization reactions were investigated.
引用
收藏
页码：2255 / 2258
页数：4
相关论文
共 50 条
  • [21] GRAFT-POLYMERIZATION OF A POLYMER MATRIX - GRAFTING OF TETRAFLUOROETHYLENE
    NEVELSKAYA, TI
    KIM, IP
    BARKALOV, IM
    JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1977, A 11 (01): : 91 - 98
  • [22] Polymerization of acrylonitrile initiated by Ce(IV)-sucrose redox system: A kinetic study
    Mahadevaiah
    Demappa, T.
    Sangappa
    Katoon, Bibi Ahamadi
    JOURNAL OF APPLIED POLYMER SCIENCE, 2008, 108 (06) : 3760 - 3768
  • [23] DETERMINATION OF HEATS OF POLYMERIZATION OF ACRYLONITRILE SORBED INTO CAPRON FIBERS
    PILYUGIN, VV
    KRITSKAYA, DA
    PONOMAREV, AN
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA B, 1986, 28 (10): : 740 - 743
  • [24] Grafting polymerization of acrylonitrile and methyl acrylate on chitosan in the presence of cobalt(III) complexes
    Baranov, I. A.
    Andriyanova, N. A.
    Mochalova, A. E.
    Sibirkin, A. A.
    Baten'kin, M. A.
    Smirnova, L. A.
    POLYMER SCIENCE SERIES B, 2012, 54 (3-4) : 167 - 174
  • [25] Grafting polymerization of acrylonitrile and methyl acrylate on chitosan in the presence of cobalt(III) complexes
    I. A. Baranov
    N. A. Andriyanova
    A. E. Mochalova
    A. A. Sibirkin
    M. A. Baten’kin
    L. A. Smirnova
    Polymer Science Series B, 2012, 54 : 167 - 174
  • [26] DETERMINATION OF SOLUBILITY PARAMETERS OF COPOLYMERS OF STYRENE AND ACRYLONITRILE
    SEYMOUR, RB
    WOOD, HC
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1976, 172 (SEP3): : 130 - 130
  • [27] ADVANCES IN THE SYNTHESIS OF GRAFT MATERIALS BY THE RADIATION GRAFTING POLYMERIZATION TECHNIQUE
    KRUL, LP
    POLIKARPOV, AP
    USPEKHI KHIMII, 1990, 59 (05) : 807 - 826
  • [28] DETERMINATION OF PROTEIN IN GRAFT CO-POLYMERS OF ACRYLONITRILE ON GELATIN
    MIECZKOWSKI, R
    MIECZKOWSKA, Z
    CHEMIA ANALITYCZNA, 1980, 25 (02): : 229 - 234
  • [29] KINETIC FEATURES OF GAMMA-RAY INITIATED GRAFT POLYMERIZATION OF ACRYLONITRILE TO POLYDIMETHYLSILOXANES
    DALTON, FL
    ROBERTS, R
    POLYMER, 1960, 1 (01) : 104 - 113
  • [30] EFFECT OF DOSE RATE ON RADIATION GRAFT POLYMERIZATION OF ACRYLONITRILE ONTO POLYVINYLCHLORIDE FIBER
    KAGEYAMA, E
    KUSAMA, Y
    UDAGAWA, A
    HASHIMOT.S
    KOG KAGAKU ZASSHI, 1971, 74 (06): : 1237 - &
12345