Graft Polymerization of Acrylonitrile-Sucrose and Determination of the Grafting Parameters

被引:0
|
作者
Sadeghi, Mohammad [1 ]
Shafeie, Fatemeh [1 ]
Mohammadinasab, Esmat [1 ]
Soleimani, Fatemeh [1 ]
机构
[1] Islamic Azad Univ, Arak Branch, Fac Sci, Dept Chem, Arak, Iran
关键词
Sucrose; Acrylonitrile; Graft copolymerization; Ceric ammonium nitrate; METHYL ACRYLATE; SODIUM ALGINATE; COPOLYMERIZATION; STARCH; POLYMERS; OXIDATION; CELLULOSE;
D O I
10.14233/ajchem.2013.13751
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Graft copolymerization of acrylonitrile onto sucrose was carried out under argon atmosphere in a homogeneous aqueous medium by using ceric ammonium nitrate as an initiator. A tentative mechanism is proposed to explain the generation of radicals and the initiation. The effect of the concentration of the initiator, monomer and polysaccharide as well as the reaction time and temperature on the graft copolymerization reactions were investigated.
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收藏
页码:2255 / 2258
页数:4
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