trans-Bis(5,5-diphenylhydantoinato-κN3)bis(propane-1,2-diamine-κ2N,N′)nickel(II)

被引:1
|
作者
Hu, Xilan
Xu, Xingyou
Wang, Daqi
Li, Xiaojiao
机构
[1] Huaihai Institute of Technology
[2] College of Chemistry and Chemical Engineering, Liaocheng University
关键词
D O I
10.1107/S1600536808038749
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The asymmetric unit of the title complex, [Ni(pht)(2)(pn)(2)] (pht is 5,5-diphenylhydantoinate and pn is propane-1,2-diamine) or [Ni(C(15)H(11)N(2)O(2))(2)(C(3)H(10)N(2))(2)], contains one-half [Ni(pht)(2)(pn)(2)] molecule. The Ni(II) atom is situated on a crystallographic center of inversion and shows a distorted octahedral coordination geometry. A three-dimensional network structure is assembled by inter-and intramolecular N-H center dot center dot center dot O = C interactions.
引用
收藏
页码:M1636 / U1446
页数:12
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