Cathodoluminescence properties of La2MoO6:Ln3+(Ln: Eu, Dy, and Sm) phosphors

被引:19
|
作者
Ayvacikli, M. [1 ]
Kaynar, Umit H. [2 ]
Karabulut, Y. [3 ]
Garcia Guinea, J. [4 ]
Bulcar, K. [5 ]
Can, N. [3 ,6 ]
机构
[1] Manisa Celal Bayar Univ, Hasan Ferdi Turgutlu Technol Fac, Mechatron Engn, Turgutlu Manisa, Turkey
[2] Bak Rcay Univ, Dept Fundamental Sci, Fac Engn & Architecture, Izmir, Turkey
[3] Manisa Celal Bayar Univ, Fac Arts & Sci, Dept Phys, TR-45010 Muradiye Manisa, Turkey
[4] Museo Nacl Ciencias Nat, Jose Gutierrez Abascal 2, Madrid 28006, Spain
[5] Cukurova Univ, Arts Sci Fac, Phys Dept, TR-01330 Adana, Turkey
[6] Jazan Univ, Phys Dept, POB 114, Jazan 45142, Saudi Arabia
关键词
La2MoO6; Gel combustion method; XRD; Cathodoluminescience; LUMINESCENCE; PR;
D O I
10.1016/j.apradiso.2020.109434
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
La2MoO6 orange-red phosphors with high efficiency incorporated with Eu, Dy and Sm have been synthesized through a gel combustion method. The influences of rare earth doping in synthesized samples were analysed by X-ray diffraction (XRD), scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS), and cathodoluminescence. Rare earth doped La(2)MoO(6 )samples show strong emission bands in the range of 400-750 nm and optimal doping concentration for all samples was 2 mol%. La2MoO6 host doped Eu ion showed intense and predominant emission peaks in 450-750 nm range. The electrical multipolar interaction contributed to the non-radiative energy transfer between Eu3+ ions in La2MoO6 host matrix. Sm doped La2MoO6 host exhibited orange-red CL emission peaks at 564, 608, 652 and 708 nm La2MoO6:Dy3+ phosphor displayed emissions at 484, 574 and 670 nm, respectively. The observed intense and sharp emission peaks indicate that La2MoO6 is promising host for lanthanides doped phosphor materials in the applications of optoelectronic.
引用
收藏
页数:7
相关论文
共 50 条
  • [31] Luminescence properties of high thermal stability Sr2ScTaO6:Ln3+ (Ln3+ = Sm3+/Dy3+) phosphors with novel double perovskite structures
    Jia, Yetong
    Xu, Denghui
    Yun, Xiangyan
    Zhou, Jun
    Sun, Jiayue
    OPTIK, 2021, 225
  • [32] Synthesis and luminescence property of Li2BaP2O7: Ln3+ (Ln = Eu, Sm) phosphors
    Wani, J. A.
    Dhoble, N. S.
    Kokode, N. S.
    Raju, B. Deva Prasad
    Dhoble, S. J.
    JOURNAL OF LUMINESCENCE, 2014, 147 : 223 - 228
  • [33] Functional applications and luminescence properties of emission tunable phosphors CaMoO4@SiO2:Ln3+ (Ln=Eu, Tb, Dy)
    Guo, Xiaoqing
    Song, Shuangju
    Jiang, Xue
    Cui, Jingru
    Li, Yunshuai
    Lv, Wenqing
    Liu, Haiyan
    Han, Yuanyuan
    Wang, Liyong
    JOURNAL OF ALLOYS AND COMPOUNDS, 2021, 857 (857)
  • [34] Synthesis and Luminescent Properties of Li3Ba2Y3(MoO4)8:Ln3+ (Ln = Eu, Tb, Dy) Phosphors for UV-LEDs
    Shang, Mengmeng
    Li, Guogang
    Kang, Xiaojiao
    Yang, Dongmei
    Lin, Jun
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2011, 158 (05) : H565 - H571
  • [35] Facile composite synthesis and photoluminescence of NaGd(MoO4)2:Ln3+ (Ln = Eu, Tb) submicrometer phosphors
    Yan, Bing
    Wu, Jianhua
    JOURNAL OF MATERIALS RESEARCH, 2009, 24 (01) : 32 - 38
  • [36] Hydrothermal synthesis and luminescence properties of uniform BaMoO4:Ln3+ (Ln = Eu, Tb, Dy, and Sm) microspheres
    Jia, Guang
    Huang, Cuimiao
    Li, Lanfen
    Wang, Chunzheng
    Song, Xingbang
    Song, Le
    Li, Zheng
    Ding, Shiwen
    OPTICAL MATERIALS, 2012, 35 (02) : 285 - 291
  • [37] Facile composite synthesis and photoluminescence of NaGd(MoO4)2: Ln3+ (Ln = Eu, Tb) submicrometer phosphors
    Bing Yan
    Jianhua Wu
    Journal of Materials Research, 2009, 24 : 32 - 38
  • [38] Tunable luminescence and energy transfer properties in YVO4:Bi3+,Ln3+ (Ln = Dy, Sm, Eu) phosphors prepared by microwave sintering method
    Yang, Lixin
    Mi, Xiaoyun
    Su, Jiangang
    Zhang, Xiyan
    Bai, Zhaohui
    Wang, Nengli
    Lin, Jun
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2018, 29 (10) : 7941 - 7951
  • [39] Heat capacity, entropy of Ln2(MoO4)3 (Ln = La, Sm, and Gd), and the high-temperature enthalpy of Ln2(MoO4)3 (Ln = Eu, Dy, and Ho)
    V. M. Lazarev
    Y. L. Suponitskiy
    S. E. Liashenko
    Russian Journal of Physical Chemistry A, 2016, 90 : 911 - 913
  • [40] Heat capacity, entropy of Ln2(MoO4)3 (Ln = La, Sm, and Gd), and the high-temperature enthalpy of Ln2(MoO4)3 (Ln = Eu, Dy, and Ho)
    Lazarev, V. M.
    Suponitskiy, Y. L.
    Liashenko, S. E.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2016, 90 (05) : 911 - 913