Ambient chemical fixation of CO2 using a highly efficient heterometallic helicate catalyst system

被引：90
|
作者：
Wang, Li
Xu, Cong
Han, Qingxin
Tang, Xiaoliang
Zhou, Panpan
Zhang, Ruilian
Gao, Guoshu
Xu, Benhua
Qin, Wenwu
Liu, Weisheng [1 ]
机构：
[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Key Lab Nonferrous Met Chem & Resources Utilizat, Lanzhou 730000, Gansu, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 18期
基金：
中国国家自然科学基金;
关键词：
METAL-ORGANIC FRAMEWORKS; CARBON-DIOXIDE; CYCLIC CARBONATES; BIFUNCTIONAL CATALYSIS; EPOXIDES; COMPLEXES; LUMINESCENT; CONVERSION; CLUSTERS; CYCLOADDITION;
D O I：
10.1039/c7cc09092g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two novel heptanuclear 3d-4f helicates have been synthesized and characterized. The helicates act as catalysts and show high catalytic activity for the coupling of CO2 and epoxides to obtain cyclic carbonates with a wide substrate scope at ambient temperature and pressure.
引用
收藏
页码：2212 / 2215
页数：4
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