Electrophilic 1,2-addition of oxoammonium salts to olefins

被引：0

作者：

Takata, T

Tsujino, Y

Nakanishi, S

Nakamura, K

Yoshida, E

Endo, T

机构：

[1] Tokyo Inst Technol, Res Lab Resources Utilizat, Midori Ku, Yokohama, Kanagawa 2268503, Japan

[2] Univ Osaka Prefecture, Grad Sch Engn, Dept Appl Chem, Sakai, Osaka 5998531, Japan

来源：

CHEMISTRY LETTERS | 1999年 / 09期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new reaction of oxoammonium salt is demonstrated. Addition of oxoammonium salts (1) to electron-rich olefins (2) such as vinyl ethers and enamines rapidly proceeded to give corresponding I,2-adducts (3) in high yields. The adducts 3 formed were further transformed by treatment with sodium ethoxide to isolable substitution products (4) in one pot reaction.

引用

页码：937 / 938

页数：2

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