Antimony/N-Hydroxyphthalimide as a Catalyst System for Cross-Dehydrogenative Coupling Reactions under Aerobic Conditions

被引：55
|
作者：
Tanoue, Arata [1 ]
Yoo, Woo-Jin [1 ]
Kobayashi, Shu [1 ]
机构：
[1] Univ Tokyo, Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2013年 / 355卷 / 2-3期
基金：
日本学术振兴会; 日本科学技术振兴机构;
关键词：
aerobic oxidation; antimony; CDC; cross-dehydrogenative coupling; N-hydroxyphthalimide (NHPI); C-H BONDS; TERTIARY-AMINES; OXIDATION; FUNCTIONALIZATION; TETRAHYDROISOQUINOLINES; OXYGEN; ALKYLATION; PHOTOREDOX; ADJACENT; COMPLEX;
D O I：
10.1002/adsc.201200999
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
In the course of our investigations to find a novel catalyst for the cross-dehydrogenative coupling (CDC) reaction, it was discovered that antimony(V) serves as a co-catalyst with N-hydroxyphthalimide (NHPI) under aerobic conditions. This is a rare example of a catalytic use of antimony for an oxidative coupling reaction.
引用
收藏
页码：269 / 273
页数：5
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