Graphene-Modified Electrode for the Selective Determination of Uric Acid Under Coexistence of Dopamine and Ascorbic Acid

被引：0
|
作者：
Chao, Mingyong [1 ]
Ma, Xinying [1 ]
Li, Xia [1 ]
机构：
[1] Heze Univ, Dept Chem & Chem Engn, Heze 274015, Peoples R China
来源：
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE | 2012年 / 7卷 / 03期
关键词：
Modified Electrode; Graphene; Electrochemistry; Uric acid; GLASSY-CARBON ELECTRODE; CHEMICALLY-MODIFIED ELECTRODE; ELECTROCHEMICAL PROPERTIES; VOLTAMMETRIC DETECTION; GRAPHITE ELECTRODE; XANTHINE; ELECTROANALYSIS; HYPOXANTHINE; SENSOR; OXIDE;
D O I：
暂无
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
A graphene-modified electrode for selective determination of uric acid was prepared. The electrochemical behaviours of uric acid at the graphene-modified electrode was investigated by cyclic voltammetry and the results showed that the graphene film on electrode exhibited excellent electrocatalytic activity for the electrochemical oxidation of uric acid in phosphate buffer solution (pH 4.0). Using the graphene-modified electrode, uric acid under coexistence of dopamine and ascorbic acid was successfully determined with good peak separation. The values of linearity range, correlation coefficient and limit of detection for uric acid were 2.00x10(-6) to 1.20x10(-4) mol/L, 0.9975 and 6.00x10(-7) mol/L respectively. The graphene-modified electrode is of excellent sensitivity, selectivity and stability, and has been successfully used for determination of uric acid in human urine.
引用
收藏
页码：2201 / 2213
页数：13
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