A palladium-catalyzed reaction of 2-alkynylbromobenzene with 2-(2-alkynyl)benzenesulfonamide

被引:9
|
作者
Xiao, Qing [1 ,2 ]
Luo, Yong [3 ]
Yan, Yujun [4 ]
Ding, Qiuping [1 ,2 ]
Wu, Jie [3 ]
机构
[1] Jiangxi Normal Univ, Key Lab Funct Small Organ Mol, Minist Educ, Nanchang 330022, Jiangxi, Peoples R China
[2] Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Jiangxi, Peoples R China
[3] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
[4] Liaohe Oilfield, Staff Hosp 2, Dept Pharm, Liaoning, Peoples R China
基金
中国国家自然科学基金;
关键词
3-COMPONENT REACTION; GENERATION; INDOLES; 2-ALKYNYLANILINE; CYCLIZATIONS; SWITCHES; DESIGN;
D O I
10.1039/c3ra40582f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A palladium-catalyzed reaction of 2-alkynylbromobenzene with 2-(2-alkynyl)benzenesulfonamide has been developed, which gives rise to 6H-benzo[f]indeno[1,2-d][1,2]thiazepine 5,5-dioxides in good yields.
引用
收藏
页码:5779 / 5784
页数:6
相关论文
共 50 条
  • [21] Ligand Bite Angle-Dependent Palladium-Catalyzed Cyclization of Propargylic Carbonates to 2-Alkynyl Azacycles or Cyclic Dienamides
    Daniels, David S. B.
    Jones, Alison S.
    Thompson, Amber L.
    Paton, Robert S.
    Anderson, Edward A.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (07) : 1915 - 1920
  • [22] Synthesis of indenes via palladium-catalyzed carboannulation of diethyl 2-(2-(1-alkynyl)phenyl)malonate and organic halides
    Guo, LN
    Duan, XH
    Bi, HP
    Liu, XY
    Liang, YM
    JOURNAL OF ORGANIC CHEMISTRY, 2006, 71 (08): : 3325 - 3327
  • [23] Route to Pyrazolo[5,1-a]isoquinolines via a Copper-Catalyzed Tandem Reaction of 2-Alkynylbromobenzene with Pyrazole
    Pan, Xiaolin
    Luo, Yong
    Wu, Jie
    JOURNAL OF ORGANIC CHEMISTRY, 2013, 78 (11): : 5756 - 5760
  • [24] PALLADIUM-CATALYZED [3+2] CYCLOADDITION REACTION USING 2-(SULFONYLMETHYL) ALLYL OR 2-(CYANOMETHYL)ALLYL CARBONATE
    SHIMIZU, I
    OHASHI, Y
    TSUJI, J
    TETRAHEDRON LETTERS, 1984, 25 (45) : 5183 - 5186
  • [25] Palladium-Catalyzed Synthesis of 1H-Indol-3-yl Acrylates from 2-Alkynyl Arylazides and Acrylic Acids
    Li, Ping
    Zhou, Zhiqiang
    Yang, Fan
    Xu, Yao
    Zhang, Xiaoxiang
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2021, 41 (08) : 3235 - 3241
  • [26] Palladium-catalyzed carbonylative annulation reaction of 2-(1-alkynyl)benzenamines: Selective synthesis of 3-(Halomethylene)indolin-2-ones
    Tang, Shi
    Yu, Quan-Fu
    Peng, Peng
    Li, Jin-Heng
    Zhong, Ping
    Tang, Ri-Yuan
    ORGANIC LETTERS, 2007, 9 (17) : 3413 - 3416
  • [27] Synthesis of 3,3-Disubstituted Oxindoles by Palladium-Catalyzed Tandem Reaction of 2-(Alkynyl)aryl Isocyanates with Benzylic Alcohols
    Toyoshima, Takeharu
    Mikano, Yusuke
    Miura, Tomoya
    Murakami, Masahiro
    ORGANIC LETTERS, 2010, 12 (20) : 4584 - 4587
  • [28] Syntheses of 2-(pentafluorophenyl)thiophene derivatives via the palladium-catalyzed Suzuki reaction
    Takimiya, K
    Niihara, N
    Otsubo, T
    SYNTHESIS-STUTTGART, 2005, (10): : 1589 - 1592
  • [29] NOVEL PHOTOCHEMICAL-REACTION OF 2-(2-ALKYNYL)ACETOPHENONES INITIATED BY TYPE-II ABSTRACTION
    KRAVITZ, JI
    MARGARETHA, P
    AGOSTA, WC
    TETRAHEDRON LETTERS, 1991, 32 (01) : 31 - 34
  • [30] Palladium-Catalyzed Iodine-Mediated Electrophilic Annulation of 2-(1-Alkynyl)biphenyls with Disulfides
    Hu, Bo-Lun
    Pi, Sha-Sha
    Qian, Peng-Cheng
    Li, Jin-Heng
    Zhang, Xing-Guo
    JOURNAL OF ORGANIC CHEMISTRY, 2013, 78 (03): : 1300 - 1305