The thermodynamic analysis of Ni2+-Mn2+-NH3-OH--H2O in co-precipitation system was earned out, and the precursor Ni1/2Mn1/2(OH)(2) was prepared by hydroxide co-precipitation method. The analysis showed that the best pH value of mixed solution is 11 and the ammonia concentration is 0.4mol/L, when NaOH is precipitating agent and ammonia is chelating agent. When the pH value is 11, the SEM images confirm that the morphology of Ni1/2Mn1/2(OH)(2) is the best.