The thermodynamic analysis of Ni1/2Mn1/2(OH)2 prepared by hydroxide co-precipitation method

被引:3
|
作者
Gu, YiJie [1 ]
Zhang, QingGang [1 ]
Chen, YunBo [2 ]
Liu, HongQuan [1 ]
Wang, YanMin [1 ]
Hao, FeiXiang [1 ]
Liu, Peng [1 ]
Li, ShuQi [1 ]
机构
[1] Shandong Univ Sci & Technol, Coll Mat Sci & Engn, Qingdao 266590, Peoples R China
[2] China Acad Machinery Sci & Technol, Adv Manufacture Technol Ctr, Beijing 100044, Peoples R China
关键词
Lithium-ion batteries; Ni1/2Mn1/2(OH)(2); Chelating agent; CATHODE MATERIAL; BATTERIES;
D O I
10.4028/www.scientific.net/AMR.643.104
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The thermodynamic analysis of Ni2+-Mn2+-NH3-OH--H2O in co-precipitation system was earned out, and the precursor Ni1/2Mn1/2(OH)(2) was prepared by hydroxide co-precipitation method. The analysis showed that the best pH value of mixed solution is 11 and the ammonia concentration is 0.4mol/L, when NaOH is precipitating agent and ammonia is chelating agent. When the pH value is 11, the SEM images confirm that the morphology of Ni1/2Mn1/2(OH)(2) is the best.
引用
收藏
页码:104 / +
页数:2
相关论文
共 50 条
  • [1] Growth mechanisms for spherical mixed hydroxide agglomerates prepared by co-precipitation method: A case of Ni1/3Co1/3Mn1/3(OH)2
    Yang Yue
    Xu Shengming
    Xie Ming
    He Yinghe
    Huang Guoyong
    Yang Youcai
    JOURNAL OF ALLOYS AND COMPOUNDS, 2015, 619 : 846 - 853
  • [2] Effect of synthesis condition on the structure and electrochemical properties of Li[Ni1/3Mn1/3Co1/3]O2 prepared by hydroxide co-precipitation method
    Deng, C.
    Liu, L.
    Zhou, W.
    Sun, K.
    Sun, D.
    ELECTROCHIMICA ACTA, 2008, 53 (05) : 2441 - 2447
  • [3] Preparation of layered Li[Ni1/2Mn1/2]O2 by ultrasonic spray pyrolysis method
    Park, SH
    Kang, SK
    Kang, YC
    Lee, YS
    Sun, YK
    CHEMISTRY LETTERS, 2003, 32 (05) : 446 - 447
  • [4] Synthetic optimization of spherical Li[Ni1/3Mn1/3Co1/3]O2 prepared by a carbonate co-precipitation method
    Zhang, S.
    Deng, C.
    Fu, B. L.
    Yang, S. Y.
    Ma, L.
    POWDER TECHNOLOGY, 2010, 198 (03) : 373 - 380
  • [5] Effect of fluorine in the preparation of Li(Ni1/3Co1/3Mn1/3)O2 via hydroxide co-precipitation
    Dai, Ke-Hua
    Xie, Yan-Ting
    Wang, Yin-Jie
    Song, Zhao-Shuang
    Lu, Qi
    ELECTROCHIMICA ACTA, 2008, 53 (08) : 3257 - 3261
  • [6] Thermodynamic analysis of synthesis of Ni1/3Co1/3Mn1/3(OH)2 via coprecipitation
    Xiao X.-Y.
    Ye Y.-Q.
    Huanan Ligong Daxue Xuebao/Journal of South China University of Technology (Natural Science), 2010, 38 (04): : 30 - 34+44
  • [7] Cathodic behaviour of NiO-coated Li(Ni1/2Mn1/2)O2
    Reddy, MV
    Rao, GVS
    Chowdari, BVR
    ELECTROCHIMICA ACTA, 2005, 50 (16-17) : 3375 - 3382
  • [8] Cathodic performance of NiO-coated Li(Ni1/2Mn1/2)O2
    Reddy, MV
    Rao, GVS
    Chowdari, BVR
    SOLID STATE IONICS: THE SCIENCE AND TECHNOLOGY OF IONS IN MOTION, 2004, : 525 - 532
  • [9] Effect of synthesis condition on the structural and electrochemical properties of Li[Ni1/3Mn1/3Co1/3]O2 prepared by carbonate co-precipitation method
    Cho, TH
    Park, SM
    Yoshio, M
    Hirai, T
    Hideshima, Y
    JOURNAL OF POWER SOURCES, 2005, 142 (1-2) : 306 - 312
  • [10] Controllable Synthesis of Ni0.5Co0.2Mn0.3(OH)2 By a Co-precipitation Method
    Yi, Zonghui
    PROCEEDINGS OF THE 2017 5TH INTERNATIONAL CONFERENCE ON MECHATRONICS, MATERIALS, CHEMISTRY AND COMPUTER ENGINEERING (ICMMCCE 2017), 2017, 141 : 33 - 38