Hybrid thiol-ene network nanocomposites based on multi(meth) acrylate POSS

被引：50
|
作者：
Li, Liguo [1 ]
Liang, Rendong [1 ]
Li, Yajie [1 ]
Liu, Hongzhi [1 ]
Feng, Shengyu [1 ]
机构：
[1] Shandong Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Special Funct Aggregated Mat, Jinan 250100, Peoples R China
来源：
JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2013年 / 406卷
基金：
中国国家自然科学基金;
关键词：
POSS; Thiol-ene reaction; FTIR; Hybrid networks; POLYHEDRAL OLIGOMERIC SILSESQUIOXANE; REACTION-DIFFUSION; POLYMERS; KINETICS; PHOTOPOLYMERIZATION; POLYMERIZATION; CAGES; REARRANGEMENT; CHEMISTRY; ROUTE;
D O I：
10.1016/j.jcis.2013.05.044
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
First, multi(meth)acrylate functionalized POSS monomers were synthesized in this paper. Secondly, FTIR was used to evaluate the homopolymerization behaviors of multi(meth)acrylate POSS and their copolymerization behaviors in the thiol-ene reactions with octa(3-mercaptopropyl) POSS in the presence of photoinitiator. Results showed that the photopolymerization rate of multimethacrylate POSS was faster than that of multiacrylate POSS. The FTIR results also showed that the copolymerizations were dominant in the thiol-ene reactions with octa(3-mercaptopropyl) POSS, different from traditional (meth)acrylatethiol system, in which homopolymerizations were predominant. Finally, the resulted hybrid networks based on POSS were characterized by XRD, FE-SEM, DSC, and TGA. The characterization results showed that hybrid networks based on POSS were homogeneous and exhibited high thermal stability. (C) 2013 Elsevier Inc. All rights reserved.
引用
收藏
页码：30 / 36
页数：7
相关论文
共 50 条
  • [41] Effect of adding a multi-functional acrylate on the electrooptical properties of reflection gratings formed by thiol-ene photopolymerization
    Natarajan, LV
    Klosterman, J
    Tondiglia, VP
    Sutherland, RL
    Lloyd, PF
    Bunning, TJ
    OPTICAL MATERIALS IN DEFENCE SYSTEMS TECHNOLOGY, 2004, 5621 : 117 - 124
  • [42] Bioderived Thiol-Ene Emulsion Polymerization for Hybrid Latex Particles
    Stanfield, Melissa K.
    Weerts, Claudia A.
    Timilsina, Mahesh Prasad
    Smith, Jason
    Thickett, Stuart C.
    BIOMACROMOLECULES, 2024, 25 (10) : 6580 - 6590
  • [43] UV curable soybean-oil hybrid systems based on thiol-acrylate and thiol-ene-acrylate chemistry
    Zhang, Dandan
    Liang, Hongbo
    Bu, Jiang
    Xiong, Lei
    Huang, Shengmei
    Zhang, D. D.
    Liang, H. B.
    Bu, J.
    Xiong, L.
    Huang, S. M.
    JOURNAL OF APPLIED POLYMER SCIENCE, 2015, 132 (24)
  • [44] Kinetics of thiol-ene and thiol-acrylate photopolymerizations with real-time Fourier transform infrared
    Cramer, NB
    Bowman, CN
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2001, 39 (19) : 3311 - 3319
  • [45] Efficient synthesis of POSS based amphiphilic nanoparticles via thiol-ene "click" reaction to improve foam stability
    Jiang, Feng
    Chen, Yuhong
    Ye, Zhuangjie
    Pang, Shishi
    Xu, Bin
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2022, 632
  • [46] Thiol-Ene Photopolymerization: Scaling Law and Analytical Formulas for Conversion Based on Kinetic Rate and Thiol-Ene Molar Ratio
    Chen, Kuo-Ti
    Cheng, Da-Chuan
    Lin, Jui-Teng
    Liu, Hsia-Wei
    POLYMERS, 2019, 11 (10)
  • [47] Investigation of thiol-ene and thiol-ene-methacrylate based resins as dental restorative materials
    Cramer, Neil B.
    Couch, Charles L.
    Schreck, Kathleen M.
    Carioscia, Jacquelyn A.
    Boulden, Jordan E.
    Stansbury, Jeffrey W.
    Bowman, Christopher N.
    DENTAL MATERIALS, 2010, 26 (01) : 21 - 28
  • [48] Interpenetrated hybrid thiol-ene/epoxy UV-cured network with enhanced impact resistance
    Sangermano, Marco
    Roppolo, Ignazio
    Acosta Ortiz, Ricardo
    Navarro Tovar, Ana Gabriela
    Garcia Valdez, Aida E.
    Berlanga Duarte, Maria Lydia
    PROGRESS IN ORGANIC COATINGS, 2015, 78 : 244 - 248
  • [49] Thermal and photopolymerization of thiol-ene network forming systems.
    Cook, WD
    Pattison, D
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 228 : U382 - U383
  • [50] Photo-Plasticity in Thiol-ene Network Polymers - A Review
    Cook, Wayne D.
    Chen, Fei
    Nghiem, Quoc Dat
    Scott, Timothy F.
    Bowman, Christopher N.
    Chausson, Sophie
    Le Pluart, Loic
    POLYMER NETWORKS: SYNTHESIS, PROPERTIES, THEORY AND APPLICATIONS, 2010, 291-292 : 50 - +
12345