A new asymmetric Schiff base system as fluorescent chemosensor for Al3+ ion

被引：74

作者：

Azadbakht, Reza ^{[1
]}

Almasi, Tayebe ^{[1
]}

Keypour, Hassan ^{[2
]}

Rezaeivala, Majid ^{[3
]}

机构：

[1] Payame Noor Univ PNU, Dept Chem, Tehran, Iran

[2] Bu Ali Univ, Fac Chem, Hamadan, Iran

[3] Hamedan Univ Technol, Dept Chem Engn, Hamadan, Iran

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 33卷

关键词：

Chemosensors; Fluorescent probes; Naked-eye detection; Naphthalene; Aluminum ions; INTRAMOLECULAR PROTON-TRANSFER; SELECTIVE DETECTION; ALUMINUM TOXICITY; AQUEOUS-SOLUTION; HYBRID LIGAND; SCAFFOLD; SENSOR; PROBE; DERIVATIVES; INDICATOR;

D O I：

10.1016/j.inoche.2013.03.014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new fluorescent sensor, (E)-1-((2-((pyridin-2-ylmethyl) (2-(pyridin-2-ylmethylamino)ethyl)-amino) ethylimino)methyl) naphthalen-2-ol (HL), has been synthesized and characterized. Exhibiting absorption and fluorescence changes in the presence of Al3+ in ethanol solution, HL could be used as a colorimetric 'naked eye' and fluorescent chemosensor for the detection of Al3+ ions. The mechanism of fluorescence was based on the cation-induced inhibition of excited-state intramolecular proton transfer (ESIPT). (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：63 / 67

页数：5

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