Pulling polymers adsorbed on a striped surface

被引:8
|
作者
Iliev, G. K. [1 ]
Orlandini, E. [2 ]
Whittington, S. G. [3 ]
机构
[1] York Univ, Dept Math & Stat, Toronto, ON M3J 2R7, Canada
[2] Univ Padua, Dipartimento Fis & Astron, CNISM, I-35131 Padua, Italy
[3] Univ Toronto, Dept Chem, Toronto, ON M5S 1A1, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
AVOIDING WALK MODEL; MONTE-CARLO; HETEROGENEOUS SURFACES; STATISTICAL-MECHANICS; RANDOM COPOLYMERS; ADSORPTION;
D O I
10.1088/1751-8113/46/5/055001
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We consider the adsorption of a linear homopolymer on a striped surface where the monomers have different energies of interaction with each of the two kinds of stripe. In addition, the polymer is subject to a force that tends to desorb the polymer, and the force can be applied at different angles. We consider both a partially directed walk model and a self-avoiding walk model. We solve the problem for the partially directed walk problem essentially completely and give phase diagrams (in the force-temperature plane) for various values of the direction in which the force is applied. The phase diagrams show re-entrance phenomena and, for some force directions, degenerate ground states. We also present a low temperature treatment that helps to interpret the results from the combinatorial solution. For the self-avoiding walk model we present Monte Carlo results and show that the phase diagrams for the partially directed walk and self-avoiding walk are qualitatively similar and, at low temperatures, are in quantitative agreement.
引用
收藏
页数:16
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